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Solid Hydrogen under Ultra High Pressure

Solid Hydrogen under Ultra High Pressure
超高压下的固态氢
批准号:
07404018
负责人:
AMAYA Kiichi
金额:
$18.94万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (A)
财政年份:
1995
资助国家:
日本
项目状态:
已结题
起止时间:
1995 至 1998

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项目成果

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中文摘要
翻译
Solid hydrogen is electrically insulator at low pressure but it is expected to show conductivity under pressure at Mbar region。Our purpose is to detect,the metallization not,by indirect optical measurement,but by more direct,electrical resistance measurement。First of all,we tried to produce ultra-high pressure and to develop the techniques of electrical and magnetic measurement under the produced pressure.In fact,we developed DAC(Diamond Anvil Cell)specially designed for ultra-high pressure and succeeded to make fine electrodes with 5µm width on the pressure surface of 30µm diameter and so,we are ready for electrical resistance measurement of solid hydrogen with volume of~10ID1-8i D1cc。High pressure of 2.25 Mbar was also successfully produced and that the resistance measurement was performed there.This is now the best,record for high pressure experiment。Secondly,on the technical basis established above,we have succeeded in the study of search for metallization an…More d superconductivity under pressure,starting from alkaline earth metal Ca,Vib group of elements such as sulfur(S)and oxygen.Further,we observed,for the first time,the pressure induced superconductivity of ionic crystal CsI and simple organic crystal of C-I D26-D2I-D24-D2O,D22-D2.During the experimental process stated above,however,the expected metallization pressure value has changed from previous 1.5 Mbar to 2.5 Mbar。Now,it is reported that,the solid hydrogen is still transparent even under 3.4 Mbar and remains as insulator electrically.Our theoretical group(Miyagi et al.)Also estimates that,molecular dissociation of solid hydrogen takes place at pressures at around 4Mbar where hydrogen is metallic.So,we have to change our experimental program and to produce higher pressure.But,at present,we expect we can reach metallic hydrogen at,pressures between2Mbar and 3Mbar and at temperature of 1000℃~1500℃。Now,we started confinement and pressurization of hydrogen.Present results show the difficulty of stable confinement,because of the diffusion into the surrounding metal。There are several difficulties against the metallization of solid hydrogen but still the new experimental techniques are developed and our reports give belief on the successful finding of metallic hydrogen in near future.Less:Less
英文摘要
Solid hydrogen is electrically insulator at low pressure but it is expected to show conductivity under pressure at Mbar region. Our purpose is to detect, the metallization not, by indirect optical measurement, but by more direct, electrical resistance measurement. First of all, we tried to produce ultra-high pressure and to develop the techniques of electrical and magnetic measurement under the produced pressure. In fact, we developed DAC (diamond anvil cell) specially designed for ultra-high pressure and succeeded to make fine electrodes with 5 μm width on the pressure surface of 30 μm diameter and so, we are ready for electrical resistance measurement of solid hydrogen with volume of 〜 10ィイD1-8ィエD1cc. High pressure of 2.25 Mbar was also successfully produced and that the resistance measurement was performed there. This is now the best, record for high pressure experiment. Secondly, on the technical basis established above, we have succeeded in the study of search for metallization an … More d superconductivity under pressure, starting from alkaline earth metal Ca, Vib group of elements such as sulfur (S) and oxygen. Further, we observed, for the first time, the pressure induced superconductivity of ionic crystal CsI and simple organic crystal of CィイD26ィエD2IィイD24ィエD2OィイD22ィエD2. During the experimental process stated above, however, the expected metallization pressure value has changed from previous 1.5 Mbar to 2.5 Mbar. Now, it is reported that, the solid hydrogen is still transparent even under 3.4 Mbar and remains as insulator electrically. Our theoretical group (Miyagi et al.) also estimates that, molecular dissociation of solid hydrogen takes place at pressures at around 4 Mbar where hydrogen is metallic. So, we have to change our experimental program and to produce higher pressure. But, at present, we expect we can reach metallic hydrogen at, pressures between 2 Mbar and 3 Mbar and at temperature of 1000 ℃ 〜 1500 ℃. Now, we started confinement and pressurization of hydrogen. Present results show the difficulty of stable confinement, because of the diffusion into the surrounding metal. There are several difficulties against the metallization of solid hydrogen but still the new experimental techniques are developed and our reports give belief on the successful finding of metallic hydrogen in near future. Less
期刊论文(62)
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会议论文
M.I.Eremets et al.: "Nanosecond Pulse Laser Heating of Graphite in DAC"Rev.High Pressure Sci.& Technol.. 7. 1013-1015 (1998)
M.I.Eremets 等人:“DAC 中石墨的纳秒脉冲激光加热”Rev.高压科学。
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S. Okada, K. Shimizu, T. C. Kobayashi, K. Amaya and S. Endo: "Observation of Superconductivity of Calcium under High Pressure"Czechoslovak J. of Phys.. 46 Suppl (LT-21, Prague, 1996). S2-869-870 (1996)
S. Okada、K. Shimizu、T. C. Kobayashi、K. Amaya 和 S. Endo:“高压下钙超导性的观察”Czechoslovak J. of Phys.. 46 Suppl(LT-21,布拉格,1996)。
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共 59 条
    Search for Superconductivity of Magnetic Metals under Pressure
    • 批准号:
      11304022
    • 项目类别:
      Grant-in-Aid for Scientific Research (A)
    • 资助金额:
      $23.62万
    • 财政年份:
      1999
    • 负责人:
      AMAYA Kiichi
    • 依托单位:
    Study of Pressure Induced Phase Transition of Molecular Crystals
    • 批准号:
      05452057
    • 项目类别:
      Grant-in-Aid for General Scientific Research (B)
    • 资助金额:
      $4.35万
    • 财政年份:
      1993
    • 负责人:
      AMAYA Kiichi
    • 依托单位:
    海外基金