CREATION OF SUPPER FUNCTIONAL DYES BASED ON NEW CONCEPT

点击翻译按钮获取中文摘要

Important results obtained in this research are as follows :1. We tried appearance of metal catalystic function based on new idea of C_<60> as super atom and were successful in finding fixing nitrogen to produce NH_3 using bicapped C_<60> with gamma-cyclodextrin. This result was extremely important.2. On the other hand, we succeeded high yield synthesis of 1,3-diphenyl-2-pyrazoline ring fused C_<60>, and found the electrochemical propaties and emissivity of fluoresecnce.3. Specially, we found indolone as new 8pi system pigment in tokiirohiratake (mushroom), and protein was synthsized in photosynthesis by the protein which include indolone. This is extremely important find on natural science as comparison of carbohydrate was synthsized by chlorofile photosynthesis.