CREATION OF SUPPER FUNCTIONAL DYES BASED ON NEW CONCEPT

基于新概念的超功能染料的创造

• 批准号: 07555586
• 负责人: MATSUBARA Yoshio
• 金额: $ 2.37万
• 依托单位: KINKI UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 1995
• 资助国家: 日本
• 起止时间: 1995 至 1996
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07555586/
• 关键词: Supper Functional Dyes; 4npi (60pi, 8pi) dyes system; gamma-cyclodextrin-C_<60> dyes; Fixing nitrogen; Bicapped C_<60>; Pyrazoline ring fused C_<60> dyes; Tokiirohiratake; Indolone as new 8pi system; Supperatom; 光物性および電気化学的挙動; 酸素発生型光合成

Important results obtained in this research are as follows :1. We tried appearance of metal catalystic function based on new idea of C_<60> as super atom and were successful in finding fixing nitrogen to produce NH_3 using bicapped C_<60> with gamma-cyclodextrin. This result was extremely important.2. On the other hand, we succeeded high yield synthesis of 1,3-diphenyl-2-pyrazoline ring fused C_<60>, and found the electrochemical propaties and emissivity of fluoresecnce.3. Specially, we found indolone as new 8pi system pigment in tokiirohiratake (mushroom), and protein was synthsized in photosynthesis by the protein which include indolone. This is extremely important find on natural science as comparison of carbohydrate was synthsized by chlorofile photosynthesis.

本研究取得的重要成果如下：1.基于超原子C_(60)&gt；的新概念，我们尝试了金属催化功能的出现，并成功地找到了用C_(60)和γ-环糊精双复盖C_(60)&gt；生成NH_3的固定氮催化剂。这一结果极其重要。另一方面，我们成功地高产率合成了1，3-二苯基-2-吡唑啉环，并研究了其电化学性质和荧光发射率。特别是，我们在东芝(蘑菇)中发现了吲哚酮作为新的8pi系统色素，蛋白质在光合作用中是由含有吲哚酮的蛋白质合成的。这是自然科学上极其重要的发现，因为碳水化合物的比较是通过氯离子光合作用来合成的。

项目成果

吉田善一: "Cyclopropenones and Heteroanalogs Methods of Organic Chemistry Vol.E17d" Thieme Publisher, 90 (1996)

吉田善一：“有机化学的环丙烯酮和杂类似物方法 Vol.E17d”Thieme Publisher，90（1996）

武隈真一: "X-Ray Crystal Structure of Guaiazulenequinone and the Structures of Two New Guaiazulenone Derivatives" Chem.Lett.1996. 465-466 (1995)

Shinichi Takekuma：“愈创蓝醌醌的 X 射线晶体结构和两种新愈创蓝酮衍生物的结构”Chem.Lett.1996 (1995)。

吉田善一: "Mechanisms for(porphyrinato)iron(III)Catalyzed Oxgenation of styrenes by O_2 in the Presence of BH_4" J.Mol.Catal.(A.Chemical). 113. 51-59 (1996)

Zenichi Yoshida：“在 BH_4 存在下，(卟啉)铁 (III) 催化苯乙烯氧化的机制”J.Mol.Catal.(A.Chemical) 113. 51-59 (1996)。

松原凱男、吉田善一: "Intramolecular Charge Transfer Interaction in 1,3-Dipheny 1-2-pyrazoline Ring-Fused C_<60>" J.Org.Chem.60. 5372-5373 (1995)

Kaio Matsubara、Zenichi Yoshida：“1,3-二苯基 1-2-吡唑啉环稠合 C_<60> 中的分子内电荷转移相互作用”J.Org.Chem.60 (1995)。

松原凱男、吉田善一: "Functionalization of C_<60> with 1,3-Nitrilimine Dipole:Synthesis of 2-pyrazoline Ring-Fused C_<60>Derivatives" Chem.Lett.1996. 373-374 (1995)

Kaio Matsubara、Zenichi Yoshida：“C_<60> 与 1,3-次氮基亚胺偶极子的官能化：2-吡唑啉环稠合 C_<60> 衍生物的合成”Chem.Lett.1996 (1995)。