Origin of natural organic matters in drinking water reservoir and relationship with trihalomethane formation potential

饮用水水库天然有机质来源及其与三卤甲烷形成潜力的关系

• 批准号: 10680535
• 负责人: FURUMAI Hiroaki
• 金额: $ 2.5万
• 依托单位: the University of Tokyo
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 1998
• 资助国家: 日本
• 起止时间: 1998 至 1999
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10680535/
• 关键词: Natural organic matter; Trihalomethane formation potential; Drinking water reservoir; Pyrolysis GC; MS; GPC; Algae; Sediment; molecular weight fractionation; 溶出; 富栄養化

1. Establishment of method to characterize natural organic matter (NOM)A method was established to characterize NOM by Pyrolysis-GC/MS, GPC and UF fractionation. And a method to concentrate diluted samples such as water in drinking water reservoir was also established by utilizing reverse osmosis and freeze-dry. By these methods, we can evaluate NOM from its pyrogram, molecular weight distribution, dissolved organic matter concentration (DOC), trihalomethane formation potential (THMFP) and UV absorbance both in raw sample and fractionated one.2. Seasonal change of NOM in drinking water reservoir, Lake TsukuiIn Tsukui Lake, DOC and THMFP was higher in summer than in winter. Molecular weight fraction between 1,000 to 10,000 dalton had higher specific THMFP (=THMFP/DOC) than fraction less than 1,OOO dalton.3. Characterization of released NOM from sediment of drinking water reservoirSediment released tests were conducted with sediment and bottom layer water in Tsukui Lake. THMFP rose up to 300μg/L under aerobic condition and 764μg/L under anaerobic condition in 21 days. Anaerobic environment enhanced DOC release and increased THMFP more than aerobic one. Specific THMFP showed less difference between these two DO condition and rather stable in time (34μg/mg on average). From the viewpoint of molecular weight distribution by GPC, NOM released under anaerobic condition had three peaks in its chromatogram at 10ィイD15ィエD1, 10ィイD13ィエD1 and 10ィイD12ィエD1〜10ィイD13ィエD1 dalton, although those in aerobic condition had an additional and large peak at 10ィイD12ィエD1 dalton. As these results, we could evaluated the difference between released NOM under anaerobic and aerobic condition by molecular weight distribution while specific THMFP showed little difference.

1.天然有机物表征方法的建立了热解-GC/MS、GPC和超滤分级表征天然有机物的方法。建立了一种利用反渗透和冷冻干燥技术浓缩饮用水水库水等稀释样品的方法。通过这些方法，可以从NOM的热解谱、分子量分布、溶解有机物浓度（DOC）、三卤甲烷生成势（THMFP）和紫外吸收度等方面对NOM进行评价.饮用水水库、Tsukui湖NOM的季节变化在Tsukui湖，DOC和THMFP在夏季高于冬季。分子量在1，000至10，000道尔顿之间的组分比分子量小于1，000道尔顿的组分具有更高的比THMFP（=THMFP/DOC）。饮用水底泥中NOM释放特性研究以津井湖底泥和底层水为研究对象，进行了底泥释放试验。好氧条件下培养21 d，THMFP达到300μg/L，厌氧条件下培养21 d，THMFP达到764μg/L。厌氧环境比好氧环境更能促进DOC的释放和THMFP的增加。THMFP在两种溶解氧条件下的差异较小，且随时间变化比较稳定（平均为34μg/mg）。从GPC的分子量分布的观点来看，在厌氧条件下释放的NOM在其色谱图中在10道尔顿D15道尔顿D1、10道尔顿D13道尔顿D1和10道尔顿D12道尔顿D1、10道尔顿D13道尔顿D1道尔顿处具有三个峰，尽管在有氧条件下释放的NOM在10道尔顿D12道尔顿D1道尔顿处具有额外的大峰。因此，我们可以通过分子量分布来评价厌氧和好氧条件下释放的NOM之间的差异，而特定的THMFP差异不大。

项目成果

中島典之: "津久井湖底泥溶出水のトリハロメタン生成能と有機物分子量分布"第51回全国水道研究発表会講演集. (印刷中). (2000)

Noriyuki Nakajima：“津久井湖泥浸出水的三卤甲烷产生能力和有机分子量分布”第51届全国供水研究会议论文集（2000年出版）。

中島典之: "津久井湖湖水中有機物の熱分解GC/MSを用いた特性評価" 第33回日本水環境学会年会講演集. (発表予定). (1999)

Noriyuki Nakajima：“利用热解 GC/MS 对津久井湖水中的有机物进行特征评估”日本水环境学会第 33 届年会论文集（预定报告）。

中島典之: "津久井湖湖水中有機物の熱分解GC/MSを用いた特性評価"第33回日本水環境学会年会講演集. 305 (1999)

Noriyuki Nakajima：“利用热解 GC/MS 对津久井湖水中的有机物进行特征评估”日本水环境学会第 33 届年会记录 305 (1999)。

THAPA Phatta Bahadur: "Characterization of organic matter released from bottom sediment of a drinking water reservoir under aerobic and anaerobic conditions"第34回日本水環境学会年会講演集. (3月発売予定). (2000)

THAPA Phatta Bahadur：“有氧和厌氧条件下饮用水水库底部沉积物释放的有机物的特征”日本水环境学会第 34 届年会论文集（计划于 2000 年发布）。

中島典之: "津久井湖底泥溶出水のトリハロメタン生成能と有機物分子量分布"第51回全国水道研究発表会講演集. (3月発売予定). (2000)

中岛典之：《津久井湖泥浸出水的三卤甲烷生成能力和有机分子量分布》第51届全国供水研究会议论文集（预定2000年3月出版）。