Development and Application to the Spectroscopy of the Structural Characterization of 12 Group Metal Thiolato Complexes

由于锌族金属具有d^<10>的电子结构，我们无法获得大量的数据来检测和/或分析金属结合基序和金属离子。为了更深入地了解锌家族蛋白的基本配位化学，我们探索合成了锌家族硫原子配合物、二配位硫原子配合物、[M(SR)_2]M_n（M=Zn（II）、Cd（II）和Hg(II)）、三配位硫原子配合物、[M(SR)_3]_n、四配位硫原子配合物；米(SR) [HB (3 5-iPr_2pz) _3]。此外，还合成了卤代配合物[M(X){HB(3,5- ipr_2pz)_3}]。用x射线分析了这些配合物的结构信息，包括M-S距离和角度，用远红外和ft -拉曼光谱分析了M-S拉伸能，用紫外光谱分析了CT能量。本报告详细描述了配位结构和M-X距离与其理化性质的关系。

As zinc family metals have a d^<10> electronic structure, we cannot have many data for detection and/or analysis of the metal binding motifs and metal ions. In order to get more insight on the basic coordination chemistry of zinc family proteins, we explored to synthesize the zinc family thiolato complexes, two-coordinate thiolato complexes, [M(SR)_2]M_n(M=Zn(II), Cd(II), and Hg(II)), three-coordinate thiolato complexes, [M(SR)_3]_n, four-coordinate thiolato complexes ; M(SR)[HB(3,5-iPr_2pz)_3]. Moreover, halogeno complexes, [M(X){HB(3,5-iPr_2pz)_3}], were also synthesized. These complexes were characterized by X-ray analysis for their structural information, including M-S distances and angles, and by Far-IR and FT-Raman spectroscopy for M-S stretching energy, and by UV spectroscopy for CT energy. This report was described the relationship between the coordination structure as well as M-X distance and their physicochemical properties in detail.