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Role of organic solvents and characterization of the extracted species in the synergistic extraction of lanthanoids(III)

Role of organic solvents and characterization of the extracted species in the synergistic extraction of lanthanoids(III)
有机溶剂在协同萃取镧系元素(III)中的作用和萃取物的表征
批准号:
11640614
负责人:
HASEGAWA Yuko
金额:
$1.86万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
1999
资助国家:
日本
项目状态:
已结题
起止时间:
1999 至 2001

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中文摘要
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英文摘要
In order to discuss the details of synergistic extraction of lanthanoids(III) with beta-diketones (TTA and pivaloyltrifluoroacetone) and aromatic amines, the residual hydration numbers of lanthanoids(III) in the beta-diketonato chelates and the adducts of the chelates with the amine, and the complexation heat as well as the adduct formation constants have been determined. In addition, the interaction between the donor atom in the amine and the acceptor atom in organic solvents such as H in chloroform has been examined from IR spectra measured.
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Y.Hasegawa, M.Miratsu, G.R.Choppin: "Dehydration from tris [β-diketonato] lanthanoids (III) on the 1, 10-phenanthroline adduct formation across lanthanoid series"Anal. Chim. Acta. 428. 149-153 (2001)
Y.Hasekawa,M.Miratsu,G.R.Choppin:“三 [β-二酮] 镧系元素 (III) 对 1, 10-菲咯啉加合物形成的镧系元素的脱水”Anal. 428。 149-153 (2001) )
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通讯作者:
T.Ito, Y.Hasegawa: "Some Consideration about Synergistic Extraction Behavior of Rare Earths (III) with Pivaloyltrifluoroacetone and Neutral Bidentate Ligands"Solv. Extr. Res. Dev. Japan. 8. 47-62 (2001)
T.Ito,Y.Hasekawa:“关于稀土(III)与新戊酰三氟丙酮和中性二齿配体协同萃取行为的一些考虑”Solv。
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Y.Hasegawa,M.Miratsu,T.Kondo: "Trend of variation of hydration number of tris [β-diketonato] lanthanoids(III) in chloroform across lanthanoid series"Inorg.Chim.Acta. 303. 291-294 (2000)
Y.Hasekawa、M.Miratsu、T.Kondo:“氯仿中三[β-二酮]镧系元素(III) 的水合数在整个镧系元素系列中的变化趋势”Inorg.Chim.Acta 303. 291-294 (2000)。
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通讯作者:
I. Matsubayashi, Y. Hasegawa: "Thermodynamic Consideration for solvent effects in the synergistic extraction of. eurcpium(III) with pivaloyltrifluoroacetone and 1,10-phenanthroline"Anal. Sci.. 17. 221-223 (2001)
I. Matsubayashi,Y. Hasekawa:“铕 (III) 与新戊酰三氟丙酮和 1,10-菲咯啉的协同萃取中溶剂效应的热力学考虑”
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28
    Preparation of binuclear complexes using synergistic extraction and luminescence properties
    • 批准号:
      19550096
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $3.0万
    • 财政年份:
      2007
    • 负责人:
      HASEGAWA Yuko
    • 依托单位:
    Circulation system of solvent extraction database.
    • 批准号:
      07554041
    • 项目类别:
      Grant-in-Aid for Scientific Research (B)
    • 资助金额:
      $3.26万
    • 财政年份:
      1995
    • 负责人:
      HASEGAWA Yuko
    • 依托单位:
    海外基金