Evaluation of Overall Greenness of Solid-Acid Catalyzed Processes

固体酸催化工艺的整体绿色度评价

• 批准号: 12650781
• 负责人: MISONO Makoto
• 金额: $ 2.24万
• 依托单位: Kogakuin University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2000
• 资助国家: 日本
• 起止时间: 2000 至 2001
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12650781/
• 关键词: Heteropolyacid; Solid acid catalyst; Pseudoliquid; Transient-response method; Solid-state NMR; Hydrogen bond; Acidic proton; Methyl t-butyl ether; 固体酸; グリーン触媒; 触媒プロセス; ライフサイクルアセスメント; ゼオライト; アミン合成

Investigating the method for the evaluation of greenness of chemical synthetic processes, the following results have been obtained.1. Quantitative evaluation of greenness of solid-acid catalyzed process.After listing up the items necessary for the evaluation, the inventory data have been collected. The existing methods for the evaluation of greenness such as eco-efficiency were also surveyed. The E-factor for reactions like Beckmann rearrangement catalyzed by a solid acid were estimated2. Experimental studies were also carried out for catalytic processes with the discussion of their greenness.The examples are Beckmann rearrangement with porous aluminosilicates, synthesis of pyroridine form butanediol, new solid acids usable in water, and heteropolyarids for selective oxygenation3. Inventory data for the estimation of greenness were collected and a trial of the evaluation was made.

对化工合成过程绿色性评价方法进行了研究，取得了以下成果.固体酸催化过程绿色度的定量评价，在列出评价所需项目后，收集了清单数据。对现有的绿色度评价方法如生态效率等进行了综述。估计了固体酸催化贝克曼重排等反应的E因子2。对催化过程进行了实验研究，并讨论了它们的绿色性，例如用多孔硅铝酸盐进行贝克曼重排、由丁二醇合成吡咯烷、可用于水的新型固体酸和用于选择性氧化的杂多酸3。收集了用于估算绿色度的库存数据，并进行了评价试验。

项目成果

御園生 誠: "グリーンケミストリーの目指すものと触媒の課題"触媒. 43(1). 7-11 (2001)

Makoto Misono：“绿色化学的目标和催化剂的挑战”Catalyst 43(1)。

Z. Hou et al.: "Synthesis of Diphenylmethane from Formalin and Benzene in a Biphasic System with 12-Tungstophophoric Acid"Chem. Commun.. 1686-1687 (2001)

Z. Hou等人：“在双相系统中用12-钨磷酸从福尔马林和苯合成二苯甲烷”Chem。

御園生誠(監修): "環境触媒とグリーンケミストリー"シーエムシー出版. 306 (2000)

Makoto Misono（导师）：“环境催化剂和绿色化学”CMC Publishing 306（2000）。

T. Yamada et al.: "Hydrophobicity of Water-Tolerant Solid Acids Characterized by Adsorptions pf Water and Benzene"Langmuir.. 16 (5). 2321-2325 (2000)

T. Yamada 等人：“以水和苯的吸附为特征的耐水固体酸的疏水性”Langmuir.. 16 (5)。

Y. Nishiyama et al.: "High Turnover Numbers for the Catalytic Selective epoxidation of Alkenes with 1 atm of Molecular Oxygen"Angew. Chem.. 19. 3639-3641 (2001)

Y. Nishiyama 等人：“1 atm 分子氧催化选择性环氧化烯烃的高周转数”Angew。