Synthesis of new functional materials by assembly of lantern-type dinuclear complexes

灯笼型双核配合物组装合成新型功能材料

• 批准号: 20550066
• 负责人: HANDA Makoto
• 金额: $ 3.08万
• 依托单位: Shimane University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2008
• 资助国家: 日本
• 起止时间: 2008 至 2010
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20550066/
• 关键词: 二核錯体; 集積化; 磁性; 液晶; 置換反応; ポリマー錯体; ルテニウム; ロジウム; 機能性化合物

Assembled complexes of lantern-type dinuclear complxes composed of two metal ions and four bidentate ligands such as carboxylate ions were synthesized and characterized. Chlorido and cyanato-bridged polymers of ruthenium (II, III) carboxylate dimers with long alkyl chains have shown intra-dimer antiferromagnetisms and liquid crystalline properties. New types of assembled complexes of the lantern-type dimers were also obtained by using formamidinato and carboxylato ligands for supporting the dinuclear skeletons.

合成了由两个金属离子和羧酸离子等四双齿配体组成的灯笼型双核配合物并对其进行了表征。具有长烷基链的（II， III）羧酸钌二聚体的氯基和氰基桥接聚合物表现出二聚体内反铁磁性和液晶性质。用甲脒和羧基配体支撑双核骨架，得到了新型灯笼型二聚体的组装配合物。

项目成果

Preparation and crystal structure of tetrakis(m-pivalato-O,O')bis [(pivalic acid-O)rhodium(II)]

四(间-新戊酸-O,O)双[(新戊酸-O)铑(II)]的制备及晶体结构

• 发表时间: 2011
• 期刊: X-ray Structure Analysis Online 27
• 作者: Masahiro Mikuriya;Jinya Yamamoto;Hideaki Ishida;Daisuke Yoshioka;Makoto Handa
• 通讯作者: Makoto Handa

Preparation and crystal structure of tetrakis(m-pivalato-O,O')bis[(pivalicacid-O)rhodium(II)]

四(间-新戊酸-O,O)双[(新戊酸-O)铑(II)]的制备及晶体结构

• 发表时间: 2011
• 期刊: X-ray Structure Analysis Online
• 影响因子: 0.2
• 作者: Masahiro Mikuriya

Synthesis, Crystal Structure, and Spectral and Magnetic Properties of Chloro-Bridged Chain Complex of Dinuclear Ruthenium (II, III) 3,4,5-Triethoxybenzoate

双核3,4,5-三乙氧基苯甲酸钌(II,III)氯桥链配合物的合成、晶体结构、光谱和磁学性质

• 发表时间: 2009
• 期刊: Chem.J.Moldova 4
• 作者: Yukinari Sunatsuki;Ryohei Kawamoto;Kuni- hiro Fujita;Hisashi Maruyama;Takayoshi Suzuki;Hiroyuki Ishida;Masaaki Kojima;Seiichiro Iijima;Naohide Matsumoto;Hideaki Ishida
• 通讯作者: Hideaki Ishida

3,4,5-トリ(エトキシーd_5)安息香酸ルテニウム(II,III)二核のクロリド架橋鎖状錯体の結晶構造および磁気的性質

3,4,5-三(乙氧基d_5)苯甲酸钌(II,III)双核氯化物桥链配合物的晶体结构和磁性

• 发表时间: 2010
• 作者: Y. Mikata;A. Yamashita;A. Kawamura;H. Konno;Y. Miyamoto;S. Tamotsu;石田英晃
• 通讯作者: 石田英晃

Magnetic Properties of Iron(III) Complexes with Octakis(4-t-butyl-phenyl)corrolazine with ^<13>C-Enriched Pyrrole at the Alpha-Positions

具有α位富含^ 13 C的吡咯的八基(4-叔丁基苯基)咔咯嗪的铁(III)络合物的磁性

• 发表时间: 2010
• 作者: Toshihiko Saheki;Hitomi Ito;Akihiro Sekiguchi;Atsuyoshi Nishina;Toshihiro Sugiyama;Takashi Izumi;Itaru Kojima;Satoshi Kurahashi
• 通讯作者: Satoshi Kurahashi