Construction of novel organosupramolecular system using properties of nitrogen containing heterocyclic metal complexes
Construction of novel organosupramolecular system using properties of nitrogen containing heterocyclic metal complexes
批准号:
20550125
负责人:
KAWATO Toshio
金额:
$3.16万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2008
资助国家:
日本
项目状态:
已结题
起止时间:
2008 至 2010
中文摘要
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英文摘要
Novel supramolecular structures utilizing the characteristic of heteroaromatic compounds such as pyrazine were constructed. At the first stage of the study, a new type of reaction for 2,3,5,6-tetrakis(chloromethyl)pyrazine was developed to yield 2,6-diformyl-substituted pyrazine, which was derived to a new porphyrin compound. Metal complexation of the pyrazine ligand and a 4,4'-bipyridine analogue was successfully achieved. Resultant metal complexes as well as the new ligands were found to trap fullerenes effectively.
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2, 6-Bis(porphyrin)-substituted pyrazine : a new class of supramolecular synthon binding to a transition-metal ion and fullerene (C60)
2, 6-双(卟啉)取代的吡嗪:与过渡金属离子和富勒烯(C60)结合的新型超分子合成子
DOI:
--
发表时间:
2009
期刊:
Tetrahedron 65
影响因子:
--
作者:
[Yusaku Eda, et al.]
通讯作者:
et al.
2,6-Bis(porphyrin)-substituted pyrazine : a new class of supramolecular synthon binding to a transition-metal ion and fullerene (C60)
2,6-双(卟啉)取代的吡嗪:与过渡金属离子和富勒烯(C60)结合的新型超分子合成子
DOI:
--
发表时间:
2009
期刊:
Tetrahedron 65
影响因子:
--
作者:
[西田陽子, 生越友樹, 山岸忠明, 中本義章, Yusaku Eda ; Kennosuke Itoh ; Yoshio N.Ito ; Mamoru Fujitsuka ; Tetsuro Majima ; Toshio Kawato, Yusaku Eda ; Yoshio N.Ito ; Toshio Kawato]
通讯作者:
Yusaku Eda ; Yoshio N.Ito ; Toshio Kawato
ポルフィリン環を2,6位に有する複素芳香族化合物の合成と物性
2位和6位卟啉环杂芳族化合物的合成及物理性质
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[松原真, 江田優作, 伊藤謙之介, 伊藤芳雄, 川東利男]
通讯作者:
川東利男
ポルフィリン環を2,6位に有するピラジン誘導体のPd(II)錯体の合成とフラーレン分子の包接挙動
2位和6位卟啉环吡嗪衍生物Pd(II)配合物的合成及富勒烯分子的包合行为
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[江田優作, 伊藤謙之介, 伊藤芳雄, 藤塚守, 真嶋哲朗, 川東利男]
通讯作者:
川東利男
DOI:
10.1080/10610278.2010.487566
发表时间:
2010-06
期刊:
Supramolecular Chemistry
影响因子:
3.3
作者:
[Y. Eda;Kennosuke Itoh;Yoshio N. Ito;M. Fujitsuka;T. Majima;T. Kawato]
通讯作者:
Y. Eda;Kennosuke Itoh;Yoshio N. Ito;M. Fujitsuka;T. Majima;T. Kawato
Studies on elucidation of isomerization reaction of Schiff bases crystals and construction of novel proton flux. supramolecular systems
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批准号:14540498
-
项目类别:Grant-in-Aid for Scientific Research (C)
-
资助金额:$2.24万
-
财政年份:2002
-
负责人:KAWATO Toshio
-
依托单位:
超分子結晶中でのシッフ塩基類の異性化機構の解明と新規プロトン移動系の構築
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批准号:11640538
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项目类别:Grant-in-Aid for Scientific Research (C)
-
资助金额:$2.24万
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财政年份:1999
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负责人:KAWATO Toshio
-
依托单位:
Synthesis of salicylideneamines-inclusion compounds and elucidation of their chromotropism
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批准号:07640725
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项目类别:Grant-in-Aid for Scientific Research (C)
-
资助金额:$1.47万
-
财政年份:1995
-
负责人:KAWATO Toshio
-
依托单位:
海外基金