Elucidation and application of the functional expression mechanism of the environment-oriented mutifunctional hybrid complex
Elucidation and application of the functional expression mechanism of the environment-oriented mutifunctional hybrid complex
批准号:
20550138
负责人:
YONEMURA Toshiaki
金额:
$3.08万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2008
资助国家:
日本
项目状态:
已结题
起止时间:
2008 至 2010
中文摘要
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英文摘要
From the results of this research, it is obvious that the stereoselectivity of the dinuclear complexes to generate due to the redox ability of the complexes, and further the stereoselectivity of the polynuclear complexes were also changed by that reason. It is clarified that the polynuclear complexes having different structures were formed stereoselectively by a reaction at various ratio of the complex ion or mononuclear complex with thiocarboxylic acid. We were able to get the knowledge concerning the contribution to antimicrobe or antifungus activity. There is no examination treating such stereoselectivity so far, and it is thought that it is very significant results were obtained from the viewpoint of stereo control and function.
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NO Release Reaction of Dinitrosyl-Molybdenum Complexes with 2-Pyrimidinethiolate Derivatives
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DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[西野正理, 宮下精二, 齊藤圭二, 藤堂眞治, 中村光伸, T.Yonemura]
通讯作者:
T.Yonemura
Construction of N2S2-type Co(III) complexes with High Selectivity for Nitric Oxide and their Application to NO Sensing Electrode
一氧化氮高选择性N2S2型Co(III)配合物的构建及其在NO传感电极中的应用
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[T.Ozawa, D.Tsurudome, T.Yano, T.Inomata, Y.Funahashi, H.Masuda]
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H.Masuda
Investigation of Superoxide Reduction Mechanism in NiSOD Using Ni(II)-N_2S_2 Type Complexes
Ni(II)-N_2S_2型配合物研究NiSOD中的超氧化物还原机制
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[D.Nakane, T.Inomata, Y.Funahashi, T.Ozawa, H.Masuda]
通讯作者:
H.Masuda
Synthesis of an N3S2-type Ni(II) Complex Directed to NiSOD Active Site and Its Structural, Electrochemical, and Spectroscopic Properties
针对 NiSOD 活性位点的 N3S2 型 Ni(II) 配合物的合成及其结构、电化学和光谱性质
DOI:
10.14723/tmrsj.34.513
发表时间:
2009
期刊:
Transactions-Materials Research Society of Japan
影响因子:
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作者:
[Daisuke Nakane, Y. Funahashi, T. Ozawa, H. Masuda]
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H. Masuda
Role of Sulfenate Coordination in Nitrile Hydratase through a Model Complex Chemistry
通过模型复杂化学研究硫酸盐配位在腈水合酶中的作用
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
[林英理子, 高田忠雄, 中村光伸, 山名一成, 星山卓也, T.Ozawa]
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