Structure control of molecular assembly by cooperative effect of coordination bond and hydrogen bond.

点击翻译按钮获取中文摘要

The bifunctional ligands with a thymine moiety were synthesized for construction of DNA mimic using coordination bond. The reaction of the ligands and Pd precursor affords coordination polymers with a thymine moiety. The structure can be changed by external environment such as solvent. The pincer Pt complex with amide groups affords an assembled structure by hydrogen bonding. The relationship between the structure and emissive properties were investigated.