Regio-controlled Functionalization of Endohedral Metallofullerene

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Endohedral metallofullerenes have att racted much attention because of their novel structures and electronic and magnetic properties. In this study, I succeeded in the synthesis of new derivatives of endohedral metallofullerenes by chemical reactions, in which the substituents were regioselectively introduced onto fullerene carbon cage in a high yield. I also succeeded in the characterization of these derivativesby using of spectroscopy and a single-crystal X-ray analysis. The results in this study for functionallization of endohedral metal of ullerenes will be useful for synthesis of derivatives and developing new functional materials