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Development of Methods for Dynamic Control of the Cavity of Rhenium Calixarene Complexes

Development of Methods for Dynamic Control of the Cavity of Rhenium Calixarene Complexes
铼杯芳烃配合物空腔动态控制方法的发展
批准号:
21550069
负责人:
ISHII Youichi
金额:
$3.08万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2011

项目摘要

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中文摘要
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英文摘要
Reactions of cis-dioxorhenium complexes having a calixarene ligand with arylhydrazines or hydroxylamine have been studied in detail. The products undergo solvent-dependent isomerization concomitant with the change of the cavity shape, and this isomerization was found to be reversible in the case of the arylhydrazine derivatives. Effects of the substituents on the calixarene or arylhydrazine ligand and the kinetics of the reaction have been investigated, and the mechanism for the dynamic control of the cavity shape has been revealed successfully.
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シス(ヒドロキソ)(ニトロシル)カリックスアレーンレニウム錯体の合成と反応性
顺式(羟基)(亚硝酰基)杯芳烃铼配合物的合成及反应活性
DOI: --
发表时间: 2011
期刊:
影响因子: --
作者: [白木理沙, 白石梢, 武藤雄一郎, 石井洋一]
通讯作者: 石井洋一
DOI: 10.1246/cl.2011.1167
发表时间: 2011
期刊: Chemistry Letters
影响因子: 1.6
作者: [島田優介, 福井祥吾, 米田 宏, 鯉川雅之, 山田泰教, T.Nogami]
通讯作者: T.Nogami
Synthesis and Reactivities of cis-(Hydroxo)(nitrosyl)rhenium Calix[4]arene Complexes
顺式-(羟基)(亚硝基)铼杯[4]芳烃配合物的合成及反应活性
DOI: --
发表时间: 2011
期刊:
影响因子: --
作者: [Risa Shiraki, Kozue Shiraishi, Yuichiro Mutoh, Youichi Ishii]
通讯作者: Youichi Ishii
Reversibility of Disubstituted Vinilidene-Internal Alkyne Isomerization at Cationic Ruthenium and Iron Complexes
阳离子钌铁配合物双取代亚乙烯基-内炔异构化的可逆性
DOI: --
发表时间: 2011
期刊: Organometallics
影响因子: 2.8
作者: [Masato Murakami, Dachao Hong, Tomoyoshi Suenobu, Satoru Yamaguchi, Takashi Ogura, Shunichi Fukuzumi, 竹本真・松坂裕之, Y.Mutoh]
通讯作者: Y.Mutoh
Generalization and application of vinylidene rearrangement of disubstituted alkynes
  • 批准号:
    18K05154
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
  • 资助金额:
    $2.83万
  • 财政年份:
    2018
  • 负责人:
    ISHII Youichi
  • 依托单位:
Development and application of linear linking methods of multinucleaer complexes
  • 批准号:
    24550084
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
  • 资助金额:
    $3.49万
  • 财政年份:
    2012
  • 负责人:
    ISHII Youichi
  • 依托单位:
Effective Coordination Control by Utilizing the Cavity of Calixarenes
  • 批准号:
    18550061
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
  • 资助金额:
    $2.71万
  • 财政年份:
    2006
  • 负责人:
    ISHII Youichi
  • 依托单位:
Synthesis of Multinuclear Organometallic Cage Complexes with Structurally Unique Cyclophosphate Ligand and Their Application for Inorganic Materials
  • 批准号:
    16550101
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
  • 资助金额:
    $2.37万
  • 财政年份:
    2004
  • 负责人:
    ISHII Youichi
  • 依托单位:
海外基金