Characterization of self-assembled metal ion array in solution

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The purpose of the present research is to obtain the precise information on the metal ions array in the self-assembled systems, through the observations of transient EPR and magnetic field effects. It was found that G4 tetramer formation and stabilization were influenced by many factors such as the type of M^+ ion and the nucleotide sequence. Although a fully satisfying interpretation of the results obtained under various conditions still remains, the project will allow us to provide the aspects for future spectroscopic studies on the metal-ion array in solution.