Development of crystallized mesoporous materials including singlesite organometallic complexes and their catalytic activity with high selectivity

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Various organometallic complexes were immobilized by CVD or ligand exchange methods on inorganic-organic porous materials such as HMM-ph which involves phenylene moieties in the mesoporous silica structure or MOF which is composed of metal clusters and organic linkers. Organometallic complexes can also be immobilized on carbon nanotubes(CNT) by similar method. These unique heterogeneous catalysts can be applied for the epoxidation of alkenes or hydrosilylation of alkynes.