SOLVENT-FREE AND COMPLETE SOLID-PHASE CATALYSIS USING SOLID CATALYST・SOLID SUBSTRATE・SOLID REAGENTS

采用非均相钯/碳（Pd/C）催化剂，在常温常压下，不使用任何液体物质，对各种可还原官能团进行无溶剂固相加氢反应。Pd/C催化的铃木？在固体Pd/C和Cs_2CO_3或K_2CO_3存在下，固体溴代物和固体芳基硼酸的Miyaura偶联反应也在绝对固相条件下有效地实现，从而生成固体联芳基化合物。

The solvent-free and solid-phase hydrogenation of various reducible functionalities was efficiently catalyzed by heterogeneous palladium on carbon(Pd/C) under ambient hydrogen pressure and temperature without any liquid materials. The Pd/C-catalyzed Suzuki? Miyaura coupling reaction between solid arylbromides and solid arylboronic acids in the presence of solid Pd/C and Cs2CO3 or K2CO3 leading to the formation of solid biaryls has also been efficiently achieved under the absolute solid-phase conditions.