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Fluoro complex formation of the transactinide element, rutherfordium

Fluoro complex formation of the transactinide element, rutherfordium
反锕系元素卢瑟福的氟络合物形成
批准号:
21604009
负责人:
NAGAME Yuichiro
金额:
$3.0万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2011

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中文摘要
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英文摘要
Fluoro complex formation of the transactinide element, rutherfordium(Rf), was investigated by an ion-exchange method based on one atom-at-a-time scale together with the homologues Zr and Hf and the tetravalent pseudo-homologue Th. From the order of the complex formation strength, it was found that the ionic radius of Rf^<4+> is in between those of Zr^<4+>/Hf^<4+> and Th^<4+>. The observed result suggested that relativistic effects strongly influences the fluoro complex formation of Rf.
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Chemical equilibrium in atom-at-a-time chemistry
一次原子化学中的化学平衡
DOI: --
发表时间: 2009
期刊:
影响因子: --
作者: [A. Toyoshima, Y. Kasamatsu, K. Tsukada, M. Asai, Y. Kitatsuji, Y. Ishii, H. Toume, I. Nishinaka, H. Haba, K. Ooe, W. Sato, A. Shinohara, K. Akiyama, and Y. Nagame, A.Toyoshima, 柴田薫, 梶本亮一, Y.Kasamatsu, 中島健次, 武田全康, 武田全康, H.Haba, 柴田薫, J.Dovrak, 永目諭一郎, Y. Nagame, Y.Nagame, 豊嶋厚史, Y. Nagame, Y.Nagame]
通讯作者: Y.Nagame
Electrochemical studies of the heaviest elements at JAEA
JAEA 对最重元素的电化学研究
DOI: --
发表时间: 2009
期刊:
影响因子: --
作者: [A. Toyoshima, Y. Kasamatsu, K. Tsukada, M. Asai, Y. Kitatsuji, Y. Ishii, H. Toume, I. Nishinaka, H. Haba, K. Ooe, W. Sato, A. Shinohara, K. Akiyama, and Y. Nagame, A.Toyoshima, 柴田薫, 梶本亮一, Y.Kasamatsu, 中島健次, 武田全康, 武田全康, H.Haba, 柴田薫, J.Dovrak, 永目諭一郎, Y. Nagame, Y.Nagame, 豊嶋厚史, Y. Nagame, Y.Nagame, A.Toyoshima]
通讯作者: A.Toyoshima
DOI: --
发表时间: 2009
期刊:
影响因子: --
作者: [A. Toyoshima, Y. Kasamatsu, K. Tsukada, M. Asai, Y. Kitatsuji, Y. Ishii, H. Toume, I. Nishinaka, H. Haba, K. Ooe, W. Sato, A. Shinohara, K. Akiyama, and Y. Nagame, A.Toyoshima, 柴田薫, 梶本亮一, Y.Kasamatsu, 中島健次, 武田全康, 武田全康, H.Haba, 柴田薫, J.Dovrak, 永目諭一郎, Y. Nagame, Y.Nagame, 豊嶋厚史, Y. Nagame, Y.Nagame, A.Toyoshima, Y.Nagame, Y. Nagame, Y.Kasamatsu, A.Toyoshima, 笠松良崇, 豊嶋厚史]
通讯作者: 豊嶋厚史
Extraction chromatographic behavior of Rf, Zr, and Hf in HCl solution with styrene-divinylbenzene copolymer resin modified by TOPO(trioctylphosphine oxide)
TOPO(三辛基氧化膦)改性苯乙烯-二乙烯基苯共聚树脂对HCl溶液中Rf、Zr、Hf的萃取色谱行为
DOI: --
发表时间: 2010
期刊: J. Nucl. Radiochem. Sci
影响因子: --
作者: [Toyoshima, A.; Kasamatsu, Y.; Tsukada, K.; Asai, M.; Ishii, Y.; Toume, H.; Nishinaka, I.; Sato, T. K.; Nagame, Y.; Schadel, M.; Haba, H.; Goto, S.; Kudo, H.; Akiyama, K.; Oura, Y.; Ooe, K.; Shinohara, A.; Sueki, K.; Kratz, J. V.]
通讯作者: J. V.
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