Study on H-bonded structures in aqueous solution using laser-induced matrix isolation method

激光诱导基质隔离法研究水溶液中的氢键结构

• 批准号: 21750003
• 负责人: KAJIMOTO Shinji
• 金额: $ 3万
• 依托单位: Tohoku University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Young Scientists (B)
• 财政年份: 2009
• 资助国家: 日本
• 起止时间: 2009 至 2010
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21750003/
• 关键词: 相分離; 水素結合; レーザー温度ジャンプ法; ラマン分光法; 水和構造; 下部臨界点; レーザー; 温度ジャンプ; クラスター

The binary liquid mixture of 2-butoxyethanol (2BE) and water, which has its lower critical soluble temperature, has been studied using Raman spectroscopy. The concentration dependence of Raman spectra implies that micelle-like micro-phases forms even at room temperature when the mole fraction of 2BE is 0.01-0.1. Photo-induced phase separation and phase mixing of water and 2BE, in which spiropyran was dissolved as a photo-responsive solute, was investigated. It was found that the phase separation temperature of the merocyanine (MC) form solution was higher than that of the spiropyran (SP) form solution.

用拉曼光谱法研究了临界溶解温度较低的2-丁氧基乙醇（2BE）与水的二元液体混合物。拉曼光谱的浓度依赖性表明，即使在室温下，当2BE的摩尔分数为0.01 ~ 0.1时，也会形成胶束状微相。以螺吡喃为光响应溶质，研究了水与2BE的光诱导相分离和相混合。结果表明，merocyanine （MC）形态溶液的相分离温度高于螺吡喃（SP）形态溶液的相分离温度。

项目成果

ホームページ等。

主页等