Construction and Photovoltaic Properties of Fullerene-Encapsulated Porphyrin Nanorods

由于其在光电子学等领域的广泛应用，构建具有良好形状和结构的功能性分子组装材料引起了人们的极大兴趣。特别是，定向棒状的卟啉纳米结构也具有制造纳米材料的潜力。在这篇报告中，我们报道了由包覆的富勒烯衍生物结构控制的超分子卟啉纳米棒的制备和光物理性质。系统地进行了扫描电子显微镜(SEM)、稳态光谱、时间分辨光谱和光伏测量。

Construction of functional molecular assemblies with well-defined shapes and structures are of great interest because of a variety of applications such as optoelectronics. In particular, unidirectionally bar-shaped nanostructures of porphyrins also have potentials for fab rication of nanoscale materials. In this report, we report preparation and photophysical property of supramolecular porphyrin nanorods structurally controlled by encapsulated-fullerene derivatives. Scanning electron microscopy (SEM), steady-state and time-resolved spectroscopy, and photovoltaic measurement are systematically performed.