Creation of Revolutionary Organic Light-emitting Materials Exhibiting Highly Efficient Solid-state Emission

创造具有高效固态发光的革命性有机发光材料

• 批准号: 22350081
• 负责人: SHIMIZU Masaki
• 金额: $ 7.57万
• 依托单位: Kyoto Institute of Technology (2011-2012)Kyoto University (2010)
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2010
• 资助国家: 日本
• 起止时间: 2010 至 2012
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22350081/
• 关键词: 発光材料; 蛍光; 固体蛍光; 固体発光; パイ共役系; 量子収率; キナクリドン

We have succeeded in the development of diaminobis(styryl)-benzenes, diaminoterephthalates, bis(EWD-substituted phenyl)bis(EDG-substituted phenyl)ethenes, spirobi(2,3-diarylindene)s, and silicon-bridged 2-arylindoles as novel fluorophores that exhibit highly efficient photoluminescence in the solid states. The relationship between substituents and emission colors are disclosed in each chromophore. Some of the designed compounds are confirmed to act as superior light-emitting materials in organic light-emitting devices.

我们已经成功地开发了二氨基双（苯乙烯基）-苯，二氨基丙烯酸酯，双（EWD-取代的苯基）双（EDG-取代的苯基）乙烯，spiritone（2，3-diarylindene）s，和硅桥2-arylindoles作为新型荧光团，在固态下表现出高效的光致发光。在每个发色团中公开了取代基和发射颜色之间的关系。部分化合物被证实可作为有机电致发光器件中的上级发光材料。

项目成果

Development of Fluorinated π-conjugated Molecules Directed Toward Applications in Optoelectronic Devices

开发面向光电器件应用的氟化 π 共轭分子

• 发表时间: 2010
• 作者: Hiroyuki Seki;Shingo Kuwabara;Hiroto Kudo;and Tadatomi Nishikubo;Masaki Shimizu
• 通讯作者: Masaki Shimizu

Preparation and Properties of Silylene-bridged 2-(2-naphthyl)indole

亚硅基桥联2-(2-萘基)吲哚的制备及性能

• 发表时间: 2012
• 作者: 青山哲也;渡邉智;松本睦良;橋爪大輔;石塚亜弥;松本真哉;武藤豪志;高石和人;村中厚哉;内山真伸;J. C. Rjbierre;Isa Nishiyama;舟橋正浩;Masaki Shimizu
• 通讯作者: Masaki Shimizu

固体のままで美しく発光する有機材料

有机材料在保持固体状态的同时发出美丽的光芒

• 发表时间: 2013
• 期刊: 化学
• 作者: Keiki Kishikawa;Takahiro Inoue;Yoshiyuki Sasaki;Sumihiro Aikyo;Masahiro Takahashi;Shigeo Kohmoto;清水剛毅
• 通讯作者: 清水剛毅

Palladium-Catalyzed Synthesis and Photophysical Properties of Silicon-Bridged Biaryls

钯催化硅桥联芳基化合物的合成及其光物理性质

• 发表时间: 2011
• 作者: 松田 順治;大橋 美久;石橋 晃;Masaki Shimizu
• 通讯作者: Masaki Shimizu

Highly Efficient Blue Fluorescence from 3,2'- Silylene-Bridged 2-Phenylindoles in the Solid State

固态 3,2- 亚硅基桥接 2-苯基吲哚发出高效蓝色荧光

• DOI: 10.1021/jp201168x
• 发表时间: 2011
• 期刊: J.Phys. Chem. C
• 作者: Shimizu;M.; Mochida;K.; Hiyama;T.
• 通讯作者: T.