课题基金 / 基金详情

Study on the Synthesis and Reactivity of Transition Metal Complexes with Novel Ligands Containing Group 14 Elements

Study on the Synthesis and Reactivity of Transition Metal Complexes with Novel Ligands Containing Group 14 Elements
含14族元素新型配体过渡金属配合物的合成及反应性研究
批准号:
22550051
负责人:
SAKABA Hiroyuki
金额:
$2.25万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2010
资助国家:
日本
项目状态:
已结题
起止时间:
2010 至 2012

项目摘要

项目成果

SAKABA Hiroyuki的其他基金

相似基金

相关文献

中文摘要
翻译
点击翻译按钮获取中文摘要
英文摘要
Tungsten and Molybdenum complexes with novel ligands containing group 14 elements (i.e., the combination of carbon-silicon or carbon-germanium atoms) were synthesized. Their molecular structures were determined by X-ray crystal analyses, revealing interesting bonding nature. The dynamic behaviors in solution such as interconversion with isomers and intramolecular ligand-site exchange processes were clarified. Their reactions with various reagents were investigated to elucidate new reactivities.
期刊论文(0)
专著(0)
科研奖励(0)
会议论文
DOI: --
发表时间: 2010
期刊:
影响因子: --
作者: [坂場裕之, 他, 坂場裕之,矢部真炎,尾池浩幸,甲千寿 子, 坂場裕之, 中川圭太,權垠相,豊田耕三,坂場裕之, 中川圭太,權垠相,坂場裕之, 外崎宏樹,權垠相,坂場裕之, 吉田孝利,永井満家,坂場裕之, 新井康広,菅沼憲正,權垠相,坂場裕之, 坂場裕之, 外崎宏樹,權垠相,坂場裕之]
通讯作者: 外崎宏樹,權垠相,坂場裕之
DOI: 10.1021/om200096z
发表时间: 2011-08
期刊: Organometallics
影响因子: 2.8
作者: [H. Sakaba;H. Oike;M. Kawai;Masato Takami;C. Kabuto;M. Ray;Y. Nakao;Hirofumi Sato;S. Sakaki]
通讯作者: H. Sakaba;H. Oike;M. Kawai;Masato Takami;C. Kabuto;M. Ray;Y. Nakao;Hirofumi Sato;S. Sakaki
Reactions of Tungsten Acetylide-Silylene Complexes with Pyridines: Direct Observation of Silylene/Silyl Migration in Tungsten Acetylide and Carbyne/Vinylidene Frameworks
乙炔钨-甲硅烷基配合物与吡啶的反应:乙炔钨和卡宾/亚乙烯基骨架中甲硅烷基/甲硅烷基迁移的直接观察
DOI: 10.1021/om300772c
发表时间: 2012
期刊: Organometallics
影响因子: 2.8
作者: [西村 淳, 樋口弘之, 大和武彦, 坂場 裕之 ,尾池浩幸,新井康弘,權垠相]
通讯作者: 坂場 裕之 ,尾池浩幸,新井康弘,權垠相
Conversion of an Acetylide-Silylene Complex to an Alkenylcarbyne Complex by Consecutive Ketone Addition and Base-Induced Silanone Elimination
通过连续的酮加成和碱诱导的硅烷酮消除将乙酰化物-甲硅烷基络合物转化为烯基碳炔络合物
DOI: 10.1021/om1005879
发表时间: 2010
期刊: Organometallics
影响因子: 2.8
作者: [坂場裕之, 他, 坂場裕之,矢部真炎,尾池浩幸,甲千寿 子]
通讯作者: 坂場裕之,矢部真炎,尾池浩幸,甲千寿 子
10
    Synthesis of metal complexes with highly reactive silicon species as ligands via Si-H bond activation and their reactivity
    • 批准号:
      15550045
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $1.47万
    • 财政年份:
      2003
    • 负责人:
      SAKABA Hiroyuki
    • 依托单位:
    Studies on the Reactivity of a Labile Tungsten Acetonitrile Complex
    • 批准号:
      10640536
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $1.98万
    • 财政年份:
      1998
    • 负责人:
      SAKABA Hiroyuki
    • 依托单位:
    海外基金