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Reduction of CO2with two metal centers incorporated in a phosphamacrocycle

Reduction of CO2with two metal centers incorporated in a phosphamacrocycle
将两个金属中心纳入磷大环中还原 CO2
批准号:
22550061
负责人:
MIZUTA Tsutomu
金额:
$3.0万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2010
资助国家:
日本
项目状态:
已结题
起止时间:
2010 至 2012

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中文摘要
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英文摘要
A tetraphosphamacrocycle was synthesized by a 2:2 cyclization reaction between bisphenolA and the diphosphine in which two phosphorus centers were doubly linked with two ferrocene units. The ligand could incorporate two metal-hydride fragments such as PtH2 or CuH. These macrocyclic (PtH2)2 and (CuH)2 complexes were used for the reduction of CO2 in the presence of BH3 or HSi(OEt)3, respectively, and were found to give compounds having a methoxy group.
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会议论文
Synthesis and Crystal Structures of P-Iron-Substituted Phosphinoborane Monomers
P-铁取代的膦硼烷单体的合成和晶体结构
DOI: 10.1021/om201287s
发表时间: 2012
期刊: Organometallics
影响因子: 2.8
作者: [T. Ozawa, T. Wada, T. Inomata, Y. Funahashi, H. Masuda, 中野 元裕, Kazuyuki Kubo]
通讯作者: Kazuyuki Kubo
1,1'-フェロセニレンジホスフィド架橋鉄2 核錯体の合成とプロトン還元活性
1,1-二茂铁二磷桥联铁双核配合物的合成及质子还原活性
DOI: --
发表时间: 2012
期刊:
影响因子: --
作者: [Maeda, Y.;Hashimoto, H.; Nishioka, T., 水田 勉]
通讯作者: 水田 勉
Synthesis of Tetrahydridodiplatinum Complex Bound in Enlarged Tetraphosphamacrocycle : Two Diphosphine Platinum Units Linked in Front to Front Style
扩大四磷大环中结合的四氢化二铂配合物的合成:两个前后连接的二膦铂单元
DOI: --
发表时间: 2010
期刊:
影响因子: --
作者: [Nishiwaki, Kazuho、Yoshida, Akemi、Kubo Kazuyuki、Mizuta Tsutomu、Cavell, Ronald, G.、Miyoshi Katsuhiko, 川中伴拡, 寺本裕一, 小澤賢伯]
通讯作者: 小澤賢伯
Syntheses, Structures, and Properties of Cyclic Ferrocenophosphine Mono-, Di-, and Trimer((C_5H_4FeC_5H_4PR)_n=1-3)
环状二茂铁膦单聚体、二聚体和三聚体((C_5H_4FeC_5H_4PR)_n=1-3)的合成、结构和性能
DOI: --
发表时间: 2010
期刊: Bulletin of Japan Society of Coordination Chemistry
影响因子: --
作者: [Mizuta, Tsutomu]
通讯作者: Tsutomu
15
    Synthesis of a Variety of Metallophosphine Chelates and Elucidation and Their Functionality as Ligands
    • 批准号:
      19350032
    • 项目类别:
      Grant-in-Aid for Scientific Research (B)
    • 资助金额:
      $13.31万
    • 财政年份:
      2007
    • 负责人:
      MIZUTA Tsutomu
    • 依托单位:
    Novel multidentate ligand composed of phosphorus-bridged ferrocene units
    • 批准号:
      17550061
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $2.3万
    • 财政年份:
      2005
    • 负责人:
      MIZUTA Tsutomu
    • 依托单位:
    Preparation of metallaphophinoheterocycle complexes and their reactivity attained by cooperative interaction of two metal centers with a substrate
    • 批准号:
      15550051
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $2.43万
    • 财政年份:
      2003
    • 负责人:
      MIZUTA Tsutomu
    • 依托单位:
    Preparation of Multinuclear Complexes by a Ring-Opening Reaction of a Highly Strained Cyclic Ferrocene Unit and Their Reactivity
    • 批准号:
      13640560
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $2.24万
    • 财政年份:
      2001
    • 负责人:
      MIZUTA Tsutomu
    • 依托单位:
    海外基金