A Novel Fullerene-Appended Initiator for Living Cationic Polymerization to Synthesize Fullerene-End-Capped Polymers and their Properties

新型富勒烯活性阳离子聚合引发剂合成富勒烯封端聚合物及其性能

• 批准号: 22750178
• 负责人: MOTOYANAGI Jin
• 金额: $ 2.33万
• 依托单位: Kyoto Institute of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Young Scientists (B)
• 财政年份: 2010
• 资助国家: 日本
• 起止时间: 2010 至 2011
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22750178/
• 关键词: 精密重合; フラーレン; リビングカチオン; 特異構造高分子

Since fullerene(C_<60>) has unique physical properties, biological activity and so on, fullerene polymer conjugates are expected to provide novel advanced materials in a variety of research fields. In this research, a fullerene-substituted polymerization initiator was newly designed, and fullerene-end-capped poly(vinyl ether) s having a definite structure were synthesized by living cationic polymerization of vinyl ethers. And functional group appended vinyl ethers were also polymerized by living cationic polymerization.

由于富勒烯(C_<60>)具有独特的物理性质、生物活性等，富勒烯聚合物缀合物有望为多种研究领域提供新型先进材料。本研究新设计了富勒烯取代聚合引发剂，通过乙烯基醚的活性阳离子聚合合成了具有确定结构的富勒烯封端聚乙烯基醚。并且还通过活性阳离子聚合来聚合带有官能团的乙烯基醚。

项目成果

精密重合を用いた新規フラーレンポリマーコンジュゲートの創製

使用精密聚合创建新的富勒烯聚合物缀合物

• 发表时间: 2011
• 作者: 本柳仁;鈴木雅詞;宮原亮;箕田雅彦
• 通讯作者: 箕田雅彦

Synthesis of novel fullerene polymer conjugates by living polymerization

活性聚合合成新型富勒烯聚合物缀合物

• 发表时间: 2010
• 作者: Jin Motoyanagi;Ryo Miyabara;Masashi Suzuki;and Masahiko Minoda
• 通讯作者: and Masahiko Minoda

A Novel [60]Fullerene-appended Initiator for Living Cationic Polymerization and its Application to the Synthesis of [60]Fullerene-end-capped Poly(vinyl ether)s

新型[60]富勒烯活性阳离子聚合引发剂及其在[60]富勒烯封端聚乙烯基醚合成中的应用

• DOI: 10.1039/c2py00522k
• 发表时间: 2012
• 期刊: Polymer Chemistry
• 影响因子: 4.6
• 作者: Jin Motoyanagi;Ryo Miyabara;Masashi Suzuki;Sadao Miki;and Masahiko Minoda;Jin Motoyanagi
• 通讯作者: Jin Motoyanagi

Living Cationic Polymerization of a Coumarin-Substituted Vinyl Ether and Reversible Photoinduced Cross-linking of the Resulting Homopolymers and Amphiphilic Block Copolymers

香豆素取代的乙烯基醚的活性阳离子聚合以及所得均聚物和两亲性嵌段共聚物的可逆光致交联

• DOI: 10.1002/pola.24918
• 发表时间: 2011
• 期刊: Journal of Polymer Science Part A : Polymer Chemistry
• 作者: W.Chaikittisilp;A.Sugawara;A.Shimojima;T.Okubo;前田壮志;Jin Motoyanagi
• 通讯作者: Jin Motoyanagi

配位結合を利用したブラシ形超分子ポリマーの創製

利用配位键创建刷状超分子聚合物

• 发表时间: 2011
• 作者: 小川裕之;本柳仁;箕田雅彦
• 通讯作者: 箕田雅彦