A Novel Fullerene-Appended Initiator for Living Cationic Polymerization to Synthesize Fullerene-End-Capped Polymers and their Properties

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Since fullerene(C_<60>) has unique physical properties, biological activity and so on, fullerene polymer conjugates are expected to provide novel advanced materials in a variety of research fields. In this research, a fullerene-substituted polymerization initiator was newly designed, and fullerene-end-capped poly(vinyl ether) s having a definite structure were synthesized by living cationic polymerization of vinyl ethers. And functional group appended vinyl ethers were also polymerized by living cationic polymerization.