Development of Boron-Substituted π-Conjugated Molecules and Regulation of Their Conjugate Structure: Quinoid Structure Formation by Reduction
Development of Boron-Substituted π-Conjugated Molecules and Regulation of Their Conjugate Structure: Quinoid Structure Formation by Reduction
硼取代π共轭分子的发展及其共轭结构的调控：通过还原形成醌型结构
批准号：
22750046
负责人：
SHOJI Yoshiaki
金额：
$2.66万
依托单位：
依托单位国家：
日本
项目类别：
Grant-in-Aid for Young Scientists (B)
财政年份：
2010
资助国家：
日本
项目状态：
已结题
起止时间：
2010 至 2012
中文摘要
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英文摘要
Boron-containing π-conjugated molecules exhibit electron- and Lewis base-accepting properties due to the vacant 2p orbital of the boron atom. In addition, π-conjugated molecules having two boron substituents can dramatically alter their conjugated structure by two-electron reduction to form a quinoid structure. On the basis of this finding, versatile synthetic method for boron-containing π-conjugated molecules was newly developed. During the course of this study, highly luminescent 9,10-diboraanthracene derivatives were synthesized.
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会议论文
1,2-ジボリルベンゼン誘導体からの 9,10- ジボラアントラセン骨格形成反応
1,2-二硼基苯衍生物的9,10-二硼蒽骨架形成反应
1,2-二硼基苯衍生物的9,10-二硼蒽骨架形成反应
DOI：
--
发表时间：
2012
期刊：
影响因子：
--
作者：
[Mori, K.; Kawasaki, T.; Sueoka. S.; Akiyama, T, 根本大輔・ 庄子良晃 ・福島孝典]
通讯作者：
根本大輔・ 庄子良晃 ・福島孝典