Synthesis and properties of novel phthalocyanine analogues

新型酞菁及其亚酞菁类似物的合成是酞菁化合物化学中不可缺少的研究课题，因为它可以直接改变酞菁化合物的光学和电化学性质，但由于合成难度大，沿着这一研究方向的研究非常有限。 本研究利用酞菁和亚酞菁的合成中很少用到的新型合成前体，成功合成了一系列新型酞菁和亚酞菁化合物，并通过光谱分析和理论计算研究了它们的新性质，这些新性质受分子结构和引入的功能单元的显著影响。 此外，还利用超分子相互作用和金属配位作用研究了分子取向的控制。

Synthesis of novel phthalocyanine and subphthalocyanine analogues has been an indispensable research subject in the chemistry of phthalocyanines as it can directly lead to modification of their useful optical and electrochemical properties, but the investigation along this research direction has been very limited due to synthetic difficulty. In this research, a various novel phthalocyanines and subphthalocyanines were successfully synthesized using novel synthetic precursors, which have rarely been utilized in the syntheses of phthalocyanines and subphthalocyanines, and their novel properties, which were significantly perturbed by the molecular structures and introduced functional units, were investigated and fully demonstrated by spectroscopic analyses and theoretical calculations. Moreover, by using supramolecular interactions and metal-coordination, control of molecular alignment was also investigated.