Reversibly transformable chromatic system of nano-sized porphyrin derivative driven by the less-energy stimuli
Reversibly transformable chromatic system of nano-sized porphyrin derivative driven by the less-energy stimuli
批准号:
23550046
负责人:
HIGUCHI Hiroyuki
金额:
$3.24万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2011
资助国家:
日本
项目状态:
已结题
起止时间:
2011 至 2013
中文摘要
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英文摘要
In recent years, a variety of porphyrin-based pai-electronic conjugation systems with well-defined skeleton have been receiving much attention as good candidates for opt-electronic and electrochemical devices, because of their electronic susceptibility and processibility. In relation with such a drastic development of organic functional materials science, we originally constructed and examined the structure-property relationship of a unique octaethylporphyrin system with proton-mediated transformable functions.The results from this research project proposed as a guideline for molecular design that an introduction of the mobile 1,4-phenylene moiety into our system is very useful and important for enhancement of its sensitivity and stability to acid. Along with this line, an advanced project of other highly extended conjugation system is further in progress, aiming at the functional materials with the much higher sensitivity to outside stimuli.
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理学院 学院成就
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共 69 条
Synthesis and properties of ethylene-, vinylene-, and diacetylene-groups connected porphyrin hexamer
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批准号:18550029
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$2.62万
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财政年份:2006
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负责人:HIGUCHI Hiroyuki
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依托单位:
Syntheses and Electronic Properties of the Nickel and Palladium Complexes of the Octaethylporphyrin(M1)-(Dihexylbithiophene)_n-Octaethylporphyrin(M2) System [OEP(M1)-(DHBTh)_n-OEP(M2)] Connected with the Diacetylene Linkage. A Methodology for Molecular De
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批准号:14540489
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$1.86万
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财政年份:2002
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负责人:HIGUCHI Hiroyuki
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依托单位:
Research on Synthesis and Properties of Hybridized System between Dihexylbithiophene and Octaethylporphyrin (OEP-DHBT-OEP) Connected with the 1,3-Diacetylene Linkages
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批准号:11640528
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$2.18万
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财政年份:1999
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负责人:HIGUCHI Hiroyuki
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依托单位:
Research on Synthesis and Aromaticity of Diaza [n] annulenes
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批准号:08454199
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$2.3万
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财政年份:1996
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负责人:HIGUCHI Hiroyuki
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依托单位:
海外基金