Control of Boron Functionality Introduction Reactions Through B-H Bond Activation and Their Applications

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We investigated metal-catalyzed cross-coupling reactions of B-H compounds, which provides a direct method for conversion of C-X bonds or C-H bonds to C-B bonds. The present studies introduced several hydroboranes to participate in the catalytic borylation of aryl halides. For example, the reaction with a diazaborole showed the high level of functional group compatibility due to the low Lewis acidity. In addition, the present studies gave us some interesting information on the control of regioselectivity in the catalytic C-H borylations.