Development of interpenetrating polymer network polyimide membranes with specific binding site between polymer networks

开发具有聚合物网络之间特定结合位点的互穿聚合物网络聚酰亚胺膜

• 批准号: 24750221
• 负责人: NISHIHARA Masamichi
• 金额: $ 2.83万
• 依托单位: Kyushu University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Young Scientists (B)
• 财政年份: 2012
• 资助国家: 日本
• 起止时间: 2012-04-01 至 2014-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24750221/
• 关键词: 高分子電解質膜; 燃料電池; 電荷移動錯体; 超分子構造; semi-IPN; 架橋; 相互侵入高分子網目構造; ポリイミド

Development of polymeric materials with network formed by new concept has been carried out in this study. At first, charge-transfer complex in the polymeric films was formed between additives with small molecular weight and polyimides. The position of the additives and polyimides in the films was automatically defined by charge-transfer complex formation, and the alternatively layered structure between the additives and polyimide was formed. When the additives in the layered structure are cross-lined by a cross-linker, the additives were formed the polymer which covered the polyimides layering with the additives alternatively. In this study, development of new polymeric materials with new preparation concept (charge-transfer complex formation and cross-linking) and evaluation of the polymeric materials were carried out.

本研究进行了新概念网状聚合物材料的开发。首先，在聚合物薄膜中，小分子量添加剂与聚酰亚胺之间形成电荷转移配合物。通过电荷转移络合物的形成，添加剂和聚酰亚胺在膜中的位置被自动定义，并在添加剂和聚酰亚胺之间形成交替层状结构。当层状结构中的添加剂被交联剂交叉排列时，形成添加剂交替覆盖在聚酰亚胺层状上的聚合物。在本研究中，以新的制备理念（电荷转移络合物的形成和交联）开发了新型聚合物材料，并对聚合物材料进行了评价。

项目成果

脱フッ素化を目指した高分子電解質膜の作製とプロトン伝導性の評価

除氟聚合物电解质膜的制备及质子电导率评价

• 发表时间: 2013
• 作者: Noriyuki Kado;Mitsuaki Tokuda;Patjaree Suksawad;Yoshimasa Yamamoto;Hiroyuki Ishii and Seiichi Kawahara;西原正通
• 通讯作者: 西原正通

新たな燃料電池用高分子電解質膜—電荷移動錯体高分子複合膜-

燃料电池用新型聚合物电解质膜-电荷转移复合聚合物复合膜-

• 发表时间: 2014
• 作者: O. Chaikumpollert;Y. Yamamoto;K. Suchiva;S. Kawahara;西原正通
• 通讯作者: 西原正通

Charge-Transfer complex hybrid films consisting of sulfonated polyimide and dihydroxynaphthalenes

由磺化聚酰亚胺和二羟基萘组成的电荷转移复合杂化薄膜

• 发表时间: 2013
• 作者: Masamichi Nishihara;Liana Christiani;Aleksandar Staykov;Kazunari Sasaki
• 通讯作者: Kazunari Sasaki

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Preparation and Evaluation of Interpenetrating Polymer Network Electrolyte Membrane with Charge-Transfer Complex

电荷转移复合物互穿聚合物网络电解质膜的制备与评价

• 发表时间: 2013
• 作者: Masamichi Nishihara;Liana Christiani;Kazunari Sasaki
• 通讯作者: Kazunari Sasaki