Development of a method to control biomass pyrolysis using ionic liquid

开发利用离子液体控制生物质热解的方法

• 批准号: 24760631
• 负责人: KUDO Shinji
• 金额: $ 2.91万
• 依托单位: Kyushu University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Young Scientists (B)
• 财政年份: 2012
• 资助国家: 日本
• 起止时间: 2012-04-01 至 2014-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24760631/
• 关键词: バイオマス; セルロース; 熱分解; イオン液体

Sulfonate ionic liquids promoted dehydration of cellulose when their mixture was heated under inert gas stream, which resulted in a selective production of levoglucosenone that is a high-value added chemical. Similar results were obtained even when glucose and its oligomer and polymer were used as the source of levoglucosenone, although cellulose was the most promising starting material. On the basis of knowledge obtained in the experiment, a new and more efficient method for levoglucosenone production was proposed for the study in future.

在惰性气体流下加热磺酸盐离子液体，促进纤维素脱水，选择性生产高附加值化学品左旋葡萄糖酮。即使使用葡萄糖及其低聚物和聚合物作为左旋葡萄糖酮的来源，也得到了类似的结果，尽管纤维素是最有希望的起始材料。在此基础上，提出了一种新的、更有效的左旋葡萄糖酮生产方法，以供今后的研究。

项目成果

Intra-monomer-unit dehydration of cellulose under catalysis of ionic liquid toward selective production of levoglucosenone

离子液体催化下纤维素单体单元内脱水选择性生产左旋葡萄糖烯酮

• 发表时间: 2012
• 作者: Kento Yamasaki;Zhenwei Zhou;Shinji Kudo;Koyo Norinaga;Jun-ichiro Hayashi
• 通讯作者: Jun-ichiro Hayashi

Sulfonate Ionic Liquid as a Stable and Active Catalyst for Levoglucosenone Production from Saccharides via Catalytic Pyrolysis

• DOI: 10.3390/catal3040757
• 发表时间: 2013-12-01
• 期刊: CATALYSTS
• 影响因子: 3.9
• 作者: Kudo, Shinji;Zhou, Zhenwei;Hayashi, Jun-ichiro
• 通讯作者: Hayashi, Jun-ichiro

Catalysis of ionic liquid for selective formation of levoglucosenone from pyrolysis of cellulose

离子液体催化纤维素热解选择性形成左旋葡萄糖烯酮

• 发表时间: 2013
• 作者: S. Kudo;K. Yamasaki;Z. Zhou;K. Norinaga;J.-i. Hayashi
• 通讯作者: J.-i. Hayashi

Intra-monomer- unit dehydration of cellulose under catalysis of ionic liquid toward selective production of levoglucosenone

离子液体催化下纤维素单体单元脱水选择性生产左旋葡萄糖烯酮

• 发表时间: 2012
• 作者: K. Yamasaki;Z. Zhou;S. Kudo;K. Norinaga;J.-i. Hayashi
• 通讯作者: J.-i. Hayashi

Applications of Catalysis in the Selective Conversion of Lignocellulosic Biomass by Pyrolysis

催化在热解选择性转化木质纤维素生物质中的应用

• 发表时间: 2012
• 期刊: Journal of Novel Carbon Resource Sciences
• 作者: Shinji Kudo;Koyo Norinaga;Jun-ichiro Hayashi.
• 通讯作者: Jun-ichiro Hayashi.