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Significance of Phenolic Hydroxy Group in Lignin Acidolysis

酚羟基在木质素酸解中的意义

基本信息

批准号：
18J23098
负责人：
YE Qiaoqiao
金额：
$ 1.41万
依托单位：
The University of Tokyo
依托单位国家：
日本
项目类别：
Grant-in-Aid for JSPS Fellows
财政年份：
2018
资助国家：
日本
起止时间：
2018-04-25 至 2021-03-31
项目状态：
已结题

来源：
https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18J23098/
关键词：
Non-phenolic C6-C2-type disappearance rate order type of acid lignin acidolysis phenolic compound reactivity phenolic model compound acidolysis disappearance rate reaction route

项目摘要

Non-phenolic C6-C2-type model compounds (V’G, Enol ether, V’G-a-OMe and V’G-a-Br) were synthesized and reacted in HBr, HCl and H2SO4. The acidolysis of V’G-a-OMe indicated the intermediate compound, benzyl cation almost fully undergoes H2O addition reconverting to the starting compound in the H2SO4 system while it partially reacts into enol ether product in the HBr or HCl system. This result greatly solved the question which has been proposed since 20th why the reaction route depends on the type of acid and the disappearance rate in the order of HBr> HCl > H2SO4. Quantitative study on phenolic and non-phenolic compounds has also been carried out. The comparison between phenolic and non-phenolic compounds could suggest the significance of presence of phenolic hydroxyl group.

合成了非酚类c6 - c2型模型化合物（V 'G、烯醇醚、V 'G -a- ome和V 'G -a- br），并在HBr、HCl和H2SO4中进行了反应。V 'G-a-OMe的酸解表明中间化合物苄基阳离子在H2SO4体系中几乎完全发生H2O加成再转化为起始化合物，而在HBr或HCl体系中部分反应为烯醇醚产物。这一结果很好地解决了自20世纪20年代以来一直提出的反应路线取决于酸的种类和消失率按HBr> HCl > H2SO4顺序排列的问题。对酚类和非酚类化合物也进行了定量研究。酚类和非酚类化合物的比较表明酚羟基的存在具有重要意义。