Tribochemistry

Pyrex和/或Quartz玻璃细胞中的液体水星现象被确认为当水星在降低的压力下剧烈摇晃时，这些玻璃细胞在大气压力下剧烈摇晃（甚至在大气压力下）。我们发现，液体水星的表面被充电到负极性的同时，从玻璃到积极的一个。这是在旧科学书籍中与描述的一致，其中参考材料中的电气系列列表：-->乙酸>玻璃>-羊毛>丝绸>金属>-橡胶--的任何地方，任何原材料都显示比两个这样的材料更积极的字符，而不是任何其他的latter中的任何一个这样的材料都有一个模糊的边界。这是确认在Mercury-Glass对之间存在的最重要的一点，是怎么说的，要指出没有人能够解释为什么这样的电气系列从材料到材料。作者试着给出一个可行的解释 ... More 它包括几种物理变量组合的术语，如电离潜能、电子亲和力、氧化还原潜能，以及什么不是。在Vain中完成的试验：中观变量术语中的若干新的物理学-化学概念将是必要的，与详细的地方电子结构的知识结合在一起。新的发现在这项研究中发现的现象学上如下：（1） Observation of Hy D2 α-当细胞中的环境空气中的氢原子的线性发射是通过纯氢气体引物被小心地和广泛地替代到degas步骤;（2）在环境空气被每个气体广泛替代的情况下，首次探测到了良好溶解的氮分子和argon原子的发射谱;和（3）观察到钠原子的一种特征黄色光谱线，一. E。Na-D线，当钠金属块被分离地从液体汞中分离出来，但更接近它。一些论文为即将举行的纪念国际会议庆祝75年D1岁的教授R. D 1岁生日。S. S.贝克被困在葡萄牙，这次坠落。Less（低）

Tribo-luminescence phenomena of liquid mercury in Pyrex and/or quartz glass cells have been confirmed to occur when the mercury was heavily shaken in these glass cells under a reduced pressure (and even under the atmospheric pressure). We found that the surface of the liquid mercury is charged to the negative polarity while that of the glass to the positive one. This is in accord with the description in old science books which referred to the list of electrification series in the friction of materials: --> acetates>glass>-wool>silk>metals> -rubber-> - -, where any of the former materials shows a more positive character than any of the latter ones when two of such materials mentioned above undergo friction to each other. This was confirmed to exist between the mercury-glass pair.The most important point thereof, however, is to point out that nobody has been able to explain why such an electrification series holds from material to material. The author tried to give a plausible explanatio … More n to it in terms of a combination of several physical variables such as ionisation potential, electron affinities, oxydation-reduction potential, and what not. The trials finished in vain, however: several new physico-chemical concepts in terms of mesoscopic variables will be necessary for the explanation together with knowledge of the detailed local electronic structure.New findings obtained phenomenologically in this research are as follows: (1) observation of HィイD2αィエD2-line emission of the hydrogen atom when ambient air in the cell is carefully and extensively substituted by pure hydrogen gas prior to the degas step; (2) first detection of well dissolved emission spectra of the nitrogen molecule and the argon atoms when the ambient air is extensively substituted by each gas; and (3) observation of a characteristic yellowish spectrum line of the sodium atom, i.e., Na-D lines, when a block of sodium metal is located separably from the liquid mercury, but closely to it. Several papers have been provided for the forthcoming memorial international conference in celebration of 75ィイD1thィエD1 birthday of professor R. S. Becker held in Portugal this fall. Less