Harnessing redox-active ligands in functional metal complexes

利用功能金属配合物中的氧化还原活性配体

• 批准号: DP190100854
• 负责人: Prof Colette Boskovic
• 金额: $ 31.5万
• 依托单位: The University of Melbourne
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2019
• 资助国家: 澳大利亚
• 起止时间: 2019-01-01 至 2022-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP190100854
• 关键词: Harnessing; redox; active; ligands; functional

This project aims to synthesise and investigate metal-based molecules that can be reversibly switched between forms with different physical properties, such as colour or electrical conductivity, upon exposure to heat, light or electrical potential. The project expects to develop compounds that offer physical properties relevant for deployment in advanced materials or nanodevices. Expected outcomes of this project include elucidation of chemical routes to tuning the switchability and candidate compounds for future applications. As well as achieving important advances in fundamental chemistry, this project should provide significant benefits, such as novel materials for molecular electronics/spintronics, photoresponsive devices or sensors.

该项目旨在合成和研究金属基分子，这些分子在暴露于热、光或电势时可以在具有不同物理特性（例如颜色或导电性）的形式之间可逆地转换。该项目预计开发出具有与先进材料或纳米设备相关的物理特性的化合物。该项目的预期成果包括阐明调整可切换性的化学路线以及未来应用的候选化合物。除了在基础化学方面取得重要进展外，该项目还应提供显着的好处，例如用于分子电子学/自旋电子学、光响应器件或传感器的新型材料。