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OXIDATION STATE TUNGSTEN AND MOLYBDENUM DINITROGEN

OXIDATION STATE TUNGSTEN AND MOLYBDENUM DINITROGEN
氧化态钨和二氮钼
批准号：
3280446
负责人：
RICHARD R SCHROCK
金额：
$12.26万
依托单位：
MASSACHUSETTS INSTITUTE OF TECHNOLOGY
依托单位国家：
美国
项目类别：
财政年份：
1983
资助国家：
美国
项目状态：
已结题
起止时间：
1983-04-01 至 1986-03-31
来源：
https://reporter.nih.gov/project-details/3280446
关键词：
ammonia hydrazines molybdenum nitrogen oxidation reduction reaction tungsten

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英文摘要
We intend to prepare the first tungsten and molybdenum complexes of molecular nitrogen and partially reduced molecular nitrogen (hydrazido (1-), hydrazido (2-)) in which the metal is in its highest possible oxidation state. The object is to determine how high oxidation state species can be induced to give up their nitrogen ligand(s) in the form of hydrazine or ammonia, and in particular, to determine at what point the N-N bond scission occurs. These studies are aimed toward helping to answer the question as to how nitrogenase reduces molecular nitrogen.
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