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ELECTRIC AND MOLECULAR STRUCTURAL INVESTIGATIONS

ELECTRIC AND MOLECULAR STRUCTURAL INVESTIGATIONS
电和分子结构研究
批准号：
3854786
负责人：
R MCDIARMID
金额：
$0.0万
依托单位：
NATIONAL INSTITUTE OF DIABETES AND DIGESTIVE AND KIDNEY DISEASES
依托单位国家：
美国
项目类别：
财政年份：
--
资助国家：
美国
项目状态：
未结题
起止时间：
至
来源：
https://reporter.nih.gov/project-details/3854786
关键词：
acetone chemical bond resonance chemical structure diene electronic spectra molecular energy level molecular shape optical polarization photochemistry photon absorptiometry saturated /unsaturated bonds

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中文摘要
翻译
193nm区域的单光和双光共振光谱
英文摘要
The one- and two-photo resonant spectra of the 193 nm region of the spectrum of cyclopentadiene was measured and analyzed. The optical (1-photon) spectrum was shown to be composed of two interleaved 3p- Rydberg <- X transitions. From these spectra, the C=C bonds were deduced to be elongated in these excited states. The 2-photon spectrum was shown, by polarization-selection, to be dominated by totally symmetric false origins to two of the 3p-Rydberg <- X transitions. The absorption spectrum of the 3s-Rydberg <- X transition of acetone was measured and analyzed. The previously proposed analysis of this spectrum and model for 193 nm photodissociation of acetone were demonstrated to be incorrect.
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ELECTRIC AND MOLECULAR STRUCTURAL INVESTIGATIONS
ELECTRIC AND MOLECULAR STRUCTURAL INVESTIGATIONS
ELECTRIC AND MOLECULAR STRUCTURAL INVESTIGATIONS
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