Development of new electrochemically-primed photoredox catalysts

新型电化学底漆光氧化还原催化剂的开发

• 批准号: 2675779
• 金额: --
• 依托单位: University of Bristol
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2021
• 资助国家: 英国
• 起止时间: 2021 至 无数据
• 项目状态: 未结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-2675779
• 关键词: Development; new; electrochemically; primed; photoredox

Electrochemically-primed photoredox catalysis is a recently developed approach to generating high potential single electron oxidants. The selective excitation of the electrochemically generated radical cation leads to the high potential mediators that can engage in single electron transfer processes. This project will deliver a new family of catalysts that will be applied to a selection of difficult or novel C-H activation and functionalisation processes. The reactions developed will be applicable to the synthesis of complex molecules, for example in the pharmaceutical or agrochemical industries. The project fits into the areas of Synthetic organic chemistry and Catalysis, and will deliver new methodologies to the molecules that improve the quality of life for citizens of the UK and the rest of the world.

电化学引发的光氧化还原催化是最近发展起来的产生高电位单电子氧化剂的方法。电化学产生的自由基阳离子的选择性激发导致可以参与单电子转移过程的高电位介体。该项目将提供一个新的催化剂系列，将应用于选择困难或新颖的C-H活化和功能化过程。开发的反应将适用于复杂分子的合成，例如在制药或农业化学工业中。该项目适合合成有机化学和催化领域，并将为改善英国和世界其他地区公民生活质量的分子提供新的方法。