Nanoparticle-doped Mesoporous Silicates / Synthetic Developments and Applications in Catalysis

纳米颗粒掺杂介孔硅酸盐/合成进展及其在催化中的应用

• 批准号: EP/F009488/1
• 负责人: Duncan Bruce
• 金额: $ 41.44万
• 依托单位: University of York
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2007
• 资助国家: 英国
• 起止时间: 2007 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FF009488%2F1
• 关键词: Nanoparticle; doped; Mesoporous; Silicates; Synthetic

This proposal seeks to build upon DWB's discovery of a general route to nanoparticle-doped, nanostructured silicates that uses simple and off-the-shelf reagents in a true liquid crystal templating methodology. The proposal is in two, linked parts. In the first, the general methodology will be extended to: encompass a wider range of metals; exert control over particle size and metal oxidation state; employ block co-polymer templates to access cubic pore morphologies and to extend the preparation of bimetallic particles. The second part focuses on real-world catalytic applications using catalysts produced using this methodology, namely automotive exhaust emission control and selective hydrogenation of allylic species.

该提案旨在建立在DWB发现的纳米颗粒掺杂纳米结构硅酸盐的一般途径的基础上，该途径使用简单的现成试剂来实现真正的液晶模板方法。该提案分为两个相互关联的部分。在第一阶段，一般方法将扩大到：包括范围更广的金属；对粒度和金属氧化态进行控制；采用嵌段共聚物模板来获得立方孔形态并扩展双金属颗粒的制备。第二部分侧重于使用这种方法生产的催化剂的实际催化应用，即汽车尾气排放控制和烯丙基物种的选择性加氢。

项目成果

Mesoporous Silicas as Versatile Supports to Tune the Palladium-Catalyzed Selective Aerobic Oxidation of Allylic Alcohols

• DOI: 10.1002/cctc.201200301
• 发表时间: 2013-04-01
• 期刊: CHEMCATCHEM
• 影响因子: 4.5
• 作者: Parlett, Christopher M. A.;Bruce, Duncan W.;Wilson, Karen
• 通讯作者: Wilson, Karen

Alumina-grafted SBA-15 as a high performance support for Pd-catalysed cinnamyl alcohol selective oxidation

• DOI: 10.1016/j.cattod.2013.11.056
• 发表时间: 2014-06-15
• 期刊: CATALYSIS TODAY
• 影响因子: 5.3
• 作者: Parlett, Christopher M. A.;Durndell, Lee J.;Lee, Adam F.
• 通讯作者: Lee, Adam F.

Hierarchically Ordered Nanoporous Pd/SBA-15 Catalyst for the Aerobic Selective Oxidation of Sterically Challenging Allylic Alcohols

• DOI: 10.1021/cs400371a
• 发表时间: 2013-09-01
• 期刊: ACS CATALYSIS
• 影响因子: 12.9
• 作者: Parlett, Christopher M. A.;Keshwalla, Pooja;Lee, Adam F.
• 通讯作者: Lee, Adam F.