Synthesis and applications of polymerizable building-block heterocycles and their metal complexes

可聚合杂环结构单元及其金属配合物的合成及应用

• 批准号: 311864-2008
• 负责人: MacLean, Brian
• 金额: $ 1.46万
• 依托单位: St. Francis Xavier University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2008
• 资助国家: 加拿大
• 起止时间: 2008-01-01 至 2009-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=396526
• 关键词: Synthesis; applications; polymerizable; building; block

The research described in this proposal concerns the synthesis of novel heterocyclic structures that will ultimately be used for the development of new polymer materials. Electropolymerizable structures involving bithiazole and biimidazole cores will be used for the synthesis of polymerizable metal complexes. The helical arrangement of organic molecules around the metal center in these complexes will endow them with interesting optical, catalytic, and sensory properties. The untapped potential for these structures to act as "chiral catalysts" in electrochemical hydrogenation experiments is something that needs to be explored.

本提案中描述的研究涉及新型杂环结构的合成，这些结构最终将用于开发新的聚合物材料。 涉及联噻唑和联咪唑核的电可聚合结构将用于合成可聚合金属络合物。 在这些配合物中，有机分子围绕金属中心的螺旋排列将赋予它们有趣的光学，催化和感官特性。 这些结构在电化学氢化实验中作为“手性催化剂”的未开发潜力是需要探索的。