Chemical origins of enzymic catalysis
Chemical origins of enzymic catalysis
批准号:
5779-2007
负责人:
Guthrie, Peter
金额:
$2.77万
依托单位国家:
加拿大
项目类别:
Discovery Grants Program - Individual
财政年份:
2010
资助国家:
加拿大
项目状态:
已结题
起止时间:
2010-01-01 至 2011-12-31
中文摘要
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英文摘要
I have developed a general approach to predicting rate constants for chemical reactions from the corresponding equilibrium constants. This requires no kinetic information and generally requires only relatively low levels of MO theory to calculate distortion energies. The key assumption in my approach is that if only one thing happens to a molecule (geometry change with no change in bonding or bonding change with no change in geometry) then the energy is a quadratic function of a suitable reaction coordinate. The kinetic barrier (intrinsic barrier) for a real reaction arises from the need for more than one thing to happen for a real chemical transformation. This approach has been very successful in tests to date, both published and still in progress.
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Chemical origins of enzymic catalysis
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批准号:5779-2007
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项目类别:Discovery Grants Program - Individual
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资助金额:$2.77万
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财政年份:2011
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-2007
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项目类别:Discovery Grants Program - Individual
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资助金额:$2.77万
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财政年份:2009
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-2007
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项目类别:Discovery Grants Program - Individual
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资助金额:$2.77万
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财政年份:2008
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-2007
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项目类别:Discovery Grants Program - Individual
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资助金额:$2.77万
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财政年份:2007
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-2002
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.89万
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财政年份:2006
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-2002
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.89万
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财政年份:2005
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-2002
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.89万
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财政年份:2004
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-2002
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.89万
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财政年份:2003
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-2002
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.89万
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财政年份:2002
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-1998
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.89万
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财政年份:2001
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-1998
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.89万
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财政年份:2000
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-1998
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.89万
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财政年份:1999
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-1998
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.61万
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财政年份:1998
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-1994
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项目类别:Discovery Grants Program - Individual
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资助金额:$4.89万
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财政年份:1997
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-1994
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项目类别:Discovery Grants Program - Individual
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资助金额:$4.89万
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财政年份:1996
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-1994
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项目类别:Discovery Grants Program - Individual
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资助金额:$4.89万
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财政年份:1995
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负责人:Guthrie, Peter
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依托单位:
Chemical origins of enzymic catalysis
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批准号:5779-1994
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项目类别:Discovery Grants Program - Individual
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资助金额:$4.89万
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财政年份:1994
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负责人:Guthrie, Peter
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依托单位:
Chemical original enzymic catalysis
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批准号:5779-1991
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.2万
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财政年份:1993
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负责人:Guthrie, Peter
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依托单位:
Isothermal and isoperibol calorimeter
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批准号:138853-1993
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项目类别:Research Tools and Instruments - Category 1 (<$150,000)
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资助金额:$2.69万
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财政年份:1992
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负责人:Guthrie, Peter
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依托单位:
Chemical original enzymic catalysis
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批准号:5779-1991
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项目类别:Discovery Grants Program - Individual
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资助金额:$5.2万
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财政年份:1992
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负责人:Guthrie, Peter
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依托单位:
海外基金