The thermodynamics and statistical mechanics of nanoscale systems

纳米级系统的热力学和统计力学

• 批准号: 298398-2009
• 负责人: Bowles, Richard
• 金额: $ 2.19万
• 依托单位: University of Saskatchewan
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2013
• 资助国家: 加拿大
• 起止时间: 2013-01-01 至 2014-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=526016
• 关键词: thermodynamics; statistical; mechanics; nanoscale; systems

Nanoscale systems exhibit a rich variety of structures, quantum effects and phase transitions as a result of two primary effects: the increased importance of surface phenomena and the influence of fluctuations. We plan to develop computer simulation techniques and thermodynamic models that explicitly account for these features, then apply them to the study of phase transformations in nanosystems such as the freezing and melting of nanoparticles, the deliquescence of small atmospheric aerosols and capillarity condensation and cavitation in nanopores.

纳米尺度系统表现出丰富多样的结构，量子效应和相变作为两个主要效应的结果：表面现象的重要性增加和波动的影响。我们计划开发计算机模拟技术和热力学模型，明确说明这些功能，然后将它们应用到纳米系统中的相变研究，如纳米颗粒的冻结和融化，小的大气气溶胶的潮解和毛细作用冷凝和nanopores中的空化。