Complementary pairs for next generation self-assembled systems

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This project will employ a set of complementary pairings where separate sites fit together at metal ions in a specific fashion orthogonal to other pairings, like two jigsaw pieces, while forming a poor fit with other pairings. These pairings will allow retention and transfer of structural information. In this way, the bulk combination of relatively simple precursors will lead to self-assembled structures with well-defined sequence identity. This program will make and use complex abiotic molecules, enhancing outcomes in molecular information storage and transfer, molecular recognition and sensing, chemical transformations, and energy transport events, leading to economic and environmental benefits for Australia in industry and manufacturing.