Fundamental Studies in Solid-Liquid Separation in Oil Sands

本课题旨在研究油砂工业中两个突出的固液分离问题中的胶体科学基础问题。这些是油砂尾矿的脱水和固结（固水分离），以及从非水萃取（NAE）过程的产品沥青中去除细矿物固体（固溶剂分离）。在前者中，重点研究了残余沥青（一种可移动、可变形的第三相）、吸附沥青和聚合物引起的粘土表面润湿性对尾矿脱水的作用，以及聚合物和表面活性剂添加剂对沥青的影响及其对脱水的影响。在后者中，重点是不溶性沥青组分与悬浮矿物的相互作用，以及在NAE条件下非水有机溶剂悬浮液中产生的胶体力。******从两个固液分离问题的最终目标可以看出本研究的重要性。在尾矿的情况下，水浆（成熟的细粒尾矿）通常含有30-40 wt%的固体，目标是将其增加到>=75 wt%，以便回收。在NAE的情况下，有机溶剂悬浮液通常含有低浓度的矿物固体，但目标是将其进一步降低到<=0.03 wt%的固体，这样它就可以潜在地用作炼油厂的原料，而不需要升级器（这是资本和运营成本密集型和能源密集型的）。******这两个目标的实现都极具挑战性。预计拟议的5年探索补助金项目可以深入了解困难的原因，从而指出缓解措施。这些解决方案最终将使阿尔伯塔省和加拿大的油砂行业受益，从而实现更负责任地利用油砂资源的工艺。该研究还将有助于在沥青等不溶性和可变形材料存在的情况下进行固液分离的科学文献。该项目还将为加拿大经济和社会培养高素质人才提供机会。

This proposed project aims at studying the fundamental colloidal science issues in two prominent solid-liquid separation problems in oil sands industry. These are the dewatering and consolidation of the oil sands tailings (solid-water separation), and the removal of fine mineral solids from product bitumen of a nonaqueous extraction (NAE) process (solid-solvent separation). In the former the emphasis is on the role of residual bitumen, a mobile and deformable 3rd phase, and the clay surface wettability caused by adsorbed bitumen and polymers on tailings dewatering, as well as the effects of polymer and surfactant additives on the bitumen and the resulting effect on dewatering. In the latter, the emphasis is on the interactions of insoluble bitumen components and suspended minerals, and the resulting colloidal forces in the nonaqueous organic solvent suspension under NAE conditions. ******The importance of this research is seen from the ultimate targets of the two solid-liquid separation problems. In the tailings case, the aqueous slurry (mature fine tailings) usually contains 30-40 wt% solids and the target is to increase it to >=75 wt% ready for reclamation. In the NAE case, the organic solvent suspension usually contains low concentrations of mineral solids but the target is to lower it further to <=0.03 wt% solids so that it can potentially be used as a feed to refineries without the need of an upgrader (which is capital and operating cost intensive and energy intensive). ******Both targets are extremely challenging to achieve. It is anticipated that the proposed 5-year Discovery Grant project can provide insights to the reasons to the difficulties and thus point to mitigation measures. The solutions will ultimately benefit the oil sands industry of Alberta and Canada, leading to processes that more responsibly utilize the oil sands resources. The research will also contribute to the scientific literature on solid-liquid separation in the presence of insoluble and deformable materials such as bitumen. The project will also provide an opportunity to train highly qualified personnel for the Canadian economy and society.