Structural Changes in Minerals and their Effect on Intrinsic Properties

矿物的结构变化及其对内在性质的影响

• 批准号: RGPIN-2022-02998
• 负责人: Antao, Sytle
• 金额: $ 1.82万
• 依托单位: University of Calgary
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2022
• 资助国家: 加拿大
• 起止时间: 2022-01-01 至 2023-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=755098
• 关键词: Structural; Changes; Minerals; their; Effect

My research program examines mineral behaviour (physical, mechanical, thermodynamic, elastic, and chemical properties) as a function of pressure (P), temperature (T), composition (X), and time (t), that is, P-T-X-t conditions. Mineral behaviour provides realistic models for Earth processes because mineral properties are governed by their crystal structure. In my group, we try to answer questions such as why do solid materials have the composition, structure, and the properties that they exhibit? How do these properties change under different P and T conditions? How does the ordering of atoms in a structure change in response to P-T-X-t conditions? We use various in situ experimental techniques to investigate the processes that govern mineral stabilities and properties under ambient and non-ambient (different P and T) conditions and apply the results to Mineral Physics and Earth processes. We use experimental techniques in university laboratories and at synchrotron and neutron facilities. My group members investigate minerals that receive significant interest to the scientific community because of their technological properties and their usefulness in understanding earth processes. For example, garnet-group minerals are important because they occur over a range of P-T-X-t conditions and they preserve important records of igneous and metamorphic processes. Garnet-group minerals have important uses in lasers and automotive batteries. Some garnets are zoned, which affect their properties. Compositional zoning is well known in feldspars and about 75 other minerals, so our work will have implications for numerous minerals. Zoning in minerals must be considered in their thermodynamic behaviour and their effective use in geothermometry, geobarometry, and geochronology. Moreover, order-disorder processes affect seismic velocities and are needed for geophysical models. My HQP will learn important techniques to solve problems in the fields of mineralogy, crystallography, and materials science. Our findings have the potential to lead to significant discoveries that will benefit the Canadian economy.

我的研究项目研究矿物行为（物理，机械，热力学，弹性和化学性质）作为压力（P），温度（T），成分（X）和时间（t）的函数，即P-T-X-t条件。矿物行为为地球过程提供了现实的模型，因为矿物的性质是由它们的晶体结构决定的。在我的小组中，我们试图回答一些问题，比如为什么固体材料具有它们所表现出的组成、结构和性质？这些性质在不同的P和T条件下如何变化？结构中原子的排序如何响应P-T-X-t条件而改变？我们使用各种原位实验技术来研究环境和非环境（不同的P和T）条件下矿物稳定性和性质的过程，并将结果应用于矿物物理学和地球过程。我们在大学实验室以及同步加速器和中子设施中使用实验技术。我的小组成员调查的矿物，收到显着的兴趣，科学界，因为他们的技术特性和他们在了解地球过程的有用性。例如，石榴石族矿物很重要，因为它们出现在一系列P-T-X-t条件下，并且保存了火成岩和变质过程的重要记录。石榴石类矿物在激光器和汽车电池中有重要用途。一些石榴石是分区的，这影响了它们的性质。成分分带在长石和大约75种其他矿物中是众所周知的，因此我们的工作将对许多矿物产生影响。矿物的分带必须考虑到它们的热力学行为以及它们在地质测温、地质测压和地质年代学中的有效应用。此外，有序-无序过程影响地震速度，是地球物理模型所需要的。我的HQP将学习解决矿物学，晶体学和材料科学领域问题的重要技术。我们的发现有可能导致重大发现，这将有利于加拿大经济。