针对日用及医药化工上严峻的氯代恶臭废气净化要求，开发高效净化氯代恶臭废气的新型软多孔材料-金属-有机框架（MOF）微粒，通过对废弃物的回收与利用技术，借鉴氯代恶臭废气组分特性，采用MOF分子调控制备方法，结合现代大型仪器表征手段，优化合成出微粒尺度可控、高容量、高选择性、高强度等性能微粒；率先开展MOF微粒的分子吸附机理及动力学理论研究，建立气体吸附诱导MOF微粒发生结构相变的微观机制，揭示微粒分子吸附动力学规律；运用流体力学理论及微粒吸附行为，采用多相流、气相色谱仪等实验检测体系与验证方法，开展循环式气固微粒吸附床内微观、动态相速度、相含率、压降、吸附行为等理性优化研究，使大气排放达到国家一级排放标准GB16297-1996，获得我国自主知识产权的氯代恶臭废气净化技术。

New metal organic frameworks (MOF) micro-particles, as a kind of soft porous materials, will be prepared for the efficient purifying of chlorinated odorous gas from the daily-use and pharmaceutical chemical industry. The new synthesizing technics from wastes will be developed basing the recycling technology. Based on the molecular structures and characteristics of chlorinated odorous gas and using the molecular regulation method and modern experimental instruments, micro-particles of MOF with controllable size, high capacity, high selectivity and high strength can be prepared. The molecular adsorption mechanism and kinetics of the MOF micro-particles will be studied theoretically in order to establish the microscopic mechanism of gas adsorption-induced the MOF micro-particles structural phase transition occurs and reveal the law of adsorption kinetics of micro-particles moleculer. By means of fluid dynamics theory and the adsorption behaviors of the MOF micro-particles, and using multiphase fluids and gas chromatography assay system, the microscopic dynamic phase velocity, phase holdup, pressure drop, and adsorption behavior within the circulating gas-solid micro-particles adsorbent bed will be studied quantitatively. The exhaust gas after the purification treatment will meet the national emission standard GB16297-1996, and eventually obtain the independent intellectual property rights on the technology for purifying chlorinated odorous gas.