低感度有机过氧化物炸药的合成与性能研究

从安全性和能量水平来看，过氧化物炸药比现在广泛使用的黑索今和奥克托今等要逊色不少。但随着研究的深入，人们逐渐发现有机过氧化物是一类具有新概念的炸药，要想使其更适合于实际应用，必须探索过氧化物炸药降感的方法。本项目将系统研究有机过氧化物中过氧键的引入方法，建立安全、高选择性的有机过氧化物合成反应体系；在分子设计与理论计算的基础上，利用优化的过氧键引入反复杂有机过氧化物分子的实验室合成；并对合成分子的安定性、安全性、爆轰性等性能进行测试与计算，从而揭示有机过氧化物炸药结构与性能之间的内在联系及基本规律。通过本项目的实施，将为合成性能优良的低感度有机过氧化物炸药提供参考和指导，为探索新一代含能材料提供重要依据。

From the point of safety and energy levels, peroxide-based explosives are slighter than RDX and HMX which are used widely. With further research, scientists found that the organic peroxides are explosives with new concepts. In order to make peroxide-basede explosives more suitable for practical application, the researchers must find a way to lower the sensitivity. This project intends to research and establish a new type of efficient and highly selective system for synthesis of organic peroxides, synthesize complex organic peroxide molecules based on molecular design and theoretical calculation, and accumulate performance parameters to reveal the inherent relationship and basic laws between structure and properties. The project is expected to provide reference and guidance to synthesize low sensitivity peroxide-basede explosives that perform well, and provide important basis for further development of new generation of energetic materials.