结构与呈色机制探索是古陶瓷科技研究的重点内容之一。有学者利用穆斯鲍尔谱等方法在古代铁系釉瓷结构与呈色研究中的已取得了许多不俗成果。但囿于分析方法的局限，以铜元素着色的钧红、釉里红、祭红等古代著名铜红釉、彩瓷器的相关探索一直停滞不前。而XAFS方法作为研究物质局域结构最有力的工具之一，近年来已初步展现了其在文物结构分析的作用，有望在以铜、铁等为呈色元素古陶瓷的结构与呈色机制研究中产生新的突破。本课题将通过探索适合于铜红釉等古陶瓷结构分析的XAFS实验条件和数据分析处理方法，初步建立古陶瓷结构分析的XAFS方法体系，并将其初步应用于铜红釉的结构分析研究，结合成分分析、显微分析以及色度学分析等，可望全面深入地探索古代名瓷的组成、结构、工艺和外观间的相互关系，深入探讨其呈色机制和烧制工艺。本课题的开展有助于弘扬我国优秀的古陶瓷文化与技术，对现代陶瓷产业同样具有一定的借鉴意义。

Structure and coloring mechanism study have always been one of the focal points of scientific research on ancient ceramics. Many good results were made in such field of ancient celadon by Mossbauer spectrum or other method. But owing to defects of analysis method, the study of copper red glaze and other rare ancient ceramic was at a standstill. AFS become one of the most powerful tools of investigation on local structure, which have been applied in structural analysis of cultural relics in recent years. So this study explores suitable experimental conditions and data processing method of XAFS in ancient ceramic, which preliminary build the XAFS analysis system on ancient ceramic structure. Combined with concentration analysis, microscopic analysis and colorimetric analysis, etc. the relationship between the appearance and component, structure and processing of ancient ceramic will be explored and thoroughly discussing the coloring mechanism and the firing technology. The development of this research is not only promoting the culture and technology of ancient ceramic, but also has certain significance in modern ceramic industry.