本项目在前期研究的基础上，结合新型功能化吸附剂中金属离子物种吸附活性位可调变的特点，首次将这种新型吸附材料用于催化汽油深度吸附脱硫中。以硅基介孔分子筛为主体，硅烷化修饰表面硅羟基，以金属离子化合物为客体，采用多种合成方法，优化合成条件。选用不同组分的模拟油，利用间歇法及吸附穿透曲线技术，对吸附剂结构参数对吸附脱硫性能的影响进行考察。采用FTIR和UV-DRS光谱技术，研究吸附质与吸附剂相互作用模式。运用IGA/MS测定模型硫化物、烯烃及芳烃分子在新型功能化吸附剂上的选择性吸附和竞争吸附行为，确定并调控吸附剂中金属离子物种活性位的物相形态。采用原位FTIR、IGA/MS、吸附穿透曲线等技术，结合分子模拟计算，对活性位的分散，物相形态与吸附性能之间的构效关系等问题进行系统研究，以更好地认识新型功能化吸附剂具有优良吸附分离性能的实质，为这类新型吸附材料的合成方法的完善提供指导，从而实现催化汽油中噻吩类硫化物的深度移除。

On the basis of previous research, for the first time, a new-type functional adsorbent with the metal-ions adsorptive active sites that has adjustable characteristics, will be used for deep adsorption desulfurization of catalytic gasoline. The synthetic route of the absorbent is that the silicon-based mesoporous zeolites are used as the main body, and then the surface silicon hydroxyls are modified by using slilyl reagents, and metal-ions compounds are dispersed as the object, using a variety of synthetic methods, optimum synthetic conditions. The adsorption desulfurization performance is investigated by the structural parameters of the adsorbent, and simulated oil with different components by using the intermittent and dynamic adsorptive methods. The interaction between adsorbate and adsorbent is studied by employing FTIR and UV-DRS spectra techniques. The selective adsorption and competitive adsorption behaviors of thiophenic sulfur, olefins and aromatics molecules on the new-type functional adsorbent are investigated by using the IGA/MS coupling techniques, and then determine and modulate the phase morphology of the metal-ions active sites in the adsorbent. The structure-activity relationship between the structure of active sites and adsorptive properties of the new-type functional adsorbent, dispersion of active sites, etc., are researched systematically by using in situ FTIR, IGA/MS, the adsorption breakthrough curve, etc., and combining with the molecular simulation calculation, in order to better understand the essence of the new-type functional adsorbent which has good adsorption and separation performance, for the sake of providing a guidance for the improvement of the synthetic methods of the new-type adsorption material and realizing the depth removal of the thiophenic sulfur compounds in FCC gasoline.