围绕绿色化学中生物质精细利用的发展，在发明的将草本生物质竹材受控炭化-磺化成竹炭磺酸或胺化成竹炭咪唑的基础上，通过表面分子工程，研究利用源于细胞组织的三维多孔竹炭作骨架以咪唑作为砌块的竹炭磺酸表面键联离子液体复合膜催化活性位的构建与修饰；考察竹炭磺酸离子液体膜在α-蒎烯烯丙位氧化、环氧化、双键氧化裂解及源于蒎烯的手性菊酯类似物合成中的多功能催化作用；通过合成蒎酮酸（醛）衍生的新化合物及生测和QSAR研究，揭示合成新型手性菊酯类似物的可能性；利用DFT等计算化学的方法研究竹炭磺酸离子液体膜的催化中心上或催化域中的反应机理，深入认识底物活化与定向的制约因素；开拓源于光合作用的生物质制备有机催化材料和农药创制的新途径，为高效负载离子液体膜新技术的创立提供科学认识，促进蒎烯转化成精细化工产品和精细合成方法学的发展。

To develop the fine utilization of biomass in green chemistry, on the basis of converting herbage biomass bamboo into bamboo char sulfonic acid or bamboo char imidazole, this project focuses on building of bamboo char sulfonic acid-ionic liquids film (BCSAILs) and the modification of acidic,basic or metallic active sites on them. Bamboo, which possess three-dimensional pore structres, were charred as the framework of BCSAILs. As block unit, imidazole bonded to bamboo char with hydroxyl, carboxyl and sulfonic groups. It will be investigated that polyfunctional catalysis of BCSAILs in allylic oxidation，epoxidation ,oxidative cleavage of α-pinene and the synthsis of chiral pyrethroid analogues from α-pinene. Based on the QSAR, bioassay and synthesis of new compound derived from pinonic acid(aldehyde), the feasibility of novel chiral pyrethroid analogueswill be explored. Catalytic mechanism of BCSAILs in these reactions will research by theoretically calculation using DFT method to deeply understand the limitation aspects on activation substrates. The project aims to exploit new way to preparation organic catalytic materials and the innovation of pesticides utilizing biomass which root in photosynthesis, to afford scientific base for establishing the new technology of efficiently preparation of functionilzed ionic liquid films, and to promote development of fine chemicals from the convertion of pinene and fine synthetic methodology.