以东北林区主要造林树种落叶松为原料，以苯酚为溶剂对落叶松进行液化。以落叶松的苯酚液化物为碳源，2种典型的双亲性嵌段共聚物F127（EO106PO70EO106）、P123（EO20PO70EO20）为结构导向剂，采用软模板—水热炭化方法，采用三聚氰胺硫酸盐的自分解调控有机-有机自组装过程，力图实现由木材出发，在介观和宏观水平上合成出结构可控有序介孔微纳米炭球，并同步实现N掺杂。项目着眼于生物质碳源与软模板的有机－有机自组装过程中液化木材组分、模板剂嵌段共聚物分子作用机制，自组装过程以及演变规律，研究有序孔组成单元的生长机理，研究水热条件下碳源-模板剂前驱体胶束阵列的热转化过程，注重同时实现木基多孔炭宏观和介观结构的调控，揭示炭材料孔结构、宏观形貌的生成机制与调控机理。

In the present project, larch which is the primary forest species of Northeast China will be used as stating materials for the fabrication of carbon spheres with ordered mesoporous structure via soft-template/hydrothermal carbonization method. Phenol will be used as liquefied solvent and the liquefied larch as carbon source, 2 typical triblock copolymer with different hydrophobic/hydropholic ratio of F127 and P123 will be used structure directing agent. With the aim of elucidate the interaction pattern between of the bio-based carbon source and soft template during the organic-organic self-organization process ,formation and subsequent thermal transformation of cluster of carbon source-soft template to the ordered carbon bone will be investigated systematically. Its influence on the formation of morphology and porous structure of the obtained carbon under hydrothermal condition will be given. The formation and growth of the ordered meso-porous unit will be observed in detail. Propose the formation and control mechanism of ordered-mesoporous carbon spheres from liquified larch via soft-template/hydrothermal carbonization method. Realized the goal of porosity and morphology simultaneous control for the bio-based carbon.