发光配位聚合物材料的研究不仅是晶体工程领域的一个重要前沿， 而且其合成及构效关系等的研究也一直是材料化学领域中的研究热点之一。本课题从配位聚合物的功能性出发，依据晶体工程学原理，致力于配位聚合物材料的合成、结构和发光性能的研究。通过系列以2,6-吡啶-二甲酸为末端基的多足配体的设计、合成，并引入不同的金属源，利用扩散、水热、溶剂热及封管等实验技术，借助于改变金属-配体比例、反应温度、浓度、溶液pH值、抗衡阴离子及加入基质等合成条件，制备新型配位聚合物发光材料，并研究这些材料的光学性能及其在化学传感、温度传感、白光LED和转光农膜方面的应用。通过分析获得的配位聚合物材料的结构和性能，总结其构效关系，为建立该类配体与金属离子间的发光机制提供基础实验数据，并最终为实现配位聚合物发光材料的可控合成和制备提供理论上的支持。本项目的研究对于性能优异的发光材料的开发具有重要的理论意义和潜在的应用价值。

Study on the luminescent coordination polymer materials is not only an important frontier in the field of crystal engineering, but also has been one of the research focuses in the field of material chemistry due to the research about their design, synthesis and structure-function relationship. Given the function of the coordination polymers and based on the principle of crystal engineering, the aim of this project is to study the synthesis, structure and luminescent properties of metal organic coordination polymers. By means of the design and synthesis of series of multipodal ligands terminated with 2,6-pyridine dicarboxylic acid and the introduction of different metal sources, we intend to prepare and study the luminescence properties of the novel multifunctional coordination polymer materials which are prepared using diffusion, hydrothermal, solvothermal, and sealed tube methods by altering the metal to ligand ratio, reaction temperature, concentration, pH value and using matrix for application in chemical sensing, temperature sensing, white light LED and light conversion film. We intend to summarize the relationship on structure and luminescent properties to provide the basic experimental data for establishing luminescence mechanism between this kind of ligands and metal ions, and finally offer some theoretical support for the controllable synthesis and preparation of luminescent coordination polymer materials. The research of this project has very important scientific significance and potential application value for development of excellent luminescent materials.