合成高效催化剂和使用环境友好反应物是“绿色化学”研究人员追求的目标之一。为了提高催化剂的性能，本项目以具有仿酶氧化催化性能的Salen型锰(III)配合物和具有氧化能力的Keggin杂多酸为基本结构单元，筛选优化分子自组装环境，构筑系列Salen型锰(III)- Keggin杂多酸复合物。以双氧水氧化苯乙烯和儿茶酚为探针反应，重点考察锰核数和Salen结构变化对复合物的催化性能的影响，探究复合物的结构与其催化性能的关系，进一步研究复合物催化机理，为获得高效双官能中心复合物催化剂提供理论和实践支持。因此，开展本项目研究不仅具有理论价值，又具有广泛的应用前景，对云南石油工业的发展提供支持。

Synthesizing highly active catalysts and using environmentally friendly reactants is one of the goals of "green chemistry" researchers. In order to promote the catalysis character, this project will develop a serial inorganic-organic hybrids which contains Salen-analogue-Manganese(III) and Keggin Polyoxometalates featuring (bio-)oxidation reaction, and oriented synthesize mononuclear Salen-Mn(III) and phenoxy bridged dinuclear Salen-Mn(III) through screening and optimizing molecular self-assembly environment. With the oxidation of styrene and catechol as probe reaction and the hydrogen peroxide as oxidant, based on the research of the catalysis character of the hybrids constructed with deferent manganese nuclear and substituting ligands, furthermore, it will shed light on the relationship between the molecular structure and the catalysis property of the hybrids, providing the theoretical and practical support to obtain more active catalysis. Therefore, this investigation is not only a research field having great scientific value but also has broad prospect in industrialization.