超分子结构是构建许多复杂体系及新型功能材料的基础。研究聚合物超分子自组装过程，寻找能形成超分子有序结构的聚合物设计规律是当今化学研究的热点。本项目拟在"耦合与去耦合"的理念指导下，将具有聚合物链超分子自组装特性的聚合物、功能性二维平面结构的纳米结构基元（如卟啉及衍生物等）与不同长度非极性烷基链或极性烷基链组合，探索近10nm超分子自组装有序结构的构筑方法；考察所得超分子自组装体的超分子自组装行为及结构与性能的关系；实现纳米结构基元的高效可控组装及聚合物超分子自组装有序结构薄膜的调控。本项目对设计新型功能聚合物、丰富自组装理论具有重要意义。

Supramolecular structures is to build the foundation of many complex systems and new functional materials. Investigating the supramolecular self-assembly process of polymer chain, looking design rules of polymers capable of forming supramolecular ordered structures is hotspot chemistry. According to the guidance of "coupling and decoupling" of the design concept, the project will have the polymer with the supramolecular self-assembly properties, the functional two-dimensional nanostructural units (such as porphyrins and derivatives, etc.) and different lengths of the non-polar or polar alkyl chain alkyl chain together, exploring sub-10nm supramolecular self-assembly method to build an ordered structure; investigating supramolecular self-assembly behavior and the relationship between structure and properties of the supramolecular self-assembly；realizing efficient controlled self-assembly of the functional two-dimensional nanostructural units, and control of the polymer supermolecule ordered structure films. The project is of great significance for the design of new functional polymers and rich self-assembly theory.